Flexural Performance of Small-Scale Textile-Reinforced Concrete Beams

Textile-reinforced concrete (TRC) as a novel high-performance composite material can be used as a strengthening material and component bearing load alone. The flexural performance of TRC beams strengthened with textile reinforcement such as carbon tows was experimentally examined and associated with those of steel-reinforced concrete (SRC) beams. Through four-point bending tests, this research explores the effects of textile layers and dosages of short textile fibre on the flexural strength of concrete beams. A total of 64 prism samples of size 100 mm × 100 mm × 500 mm were made, flexure-strengthened, and tested to evaluate various characteristics and the efficiency of TRC versus SRC beams. TRC beams performed exceptionally well as supporting material in enhancing concrete’s flexural capacity; in addition, TRC’s average ultimate load effectiveness was up to 56% than that of SRC specimens. Furthermore, the maximum deflection was about 37% lesser than SRC beams. The results showed that by increasing the number of layers, the TRC’s effectiveness was significantly increased, and the failure mode became more ductile.

Electroless Plating of High-Performance Composite Pd Membranes with EDTA-Free Bath

High-performance composite Pd membranes were successfully fabricated using electroless plating with an EDTA-free bath. The plating started with employing the one-time addition of hydrazine. In the experiment, the hydrazine concentrations and plating bath volumes were systematically varied to optimize the plating. The optimum composite Pd membrane tube showed high H2 permeance of 4.4 × 10−3 mol/m2 s Pa0.5 and high selectivity of 1.6 × 104, but poor cycling stability. Then, a method of sequential addition of the hydrazine from the high to low concentrations was employed. The resultant membrane, about 6 μm thick, still exhibited a high selectivity of 6.8 × 104 as well as a much-improved plating yield and cycling stability level; this membrane outperformed the membrane made using the unmodified plating technique with the EDTA-contained bath. This result indicates the EDTA-free bath combined with the sequential addition of hydrazine is a simple, low-cost, yet effective method for preparing thin, dense composite Pd membranes featuring high hydrogen permeation flux and high thermal durability.

Preparation of High-Performance Composite Hydrogel Reinforced by Hydrophilic Modified Waste Rubber Powder

In order to reduce the environmental pollution caused by waste rubber and to realize the recycling of resources, we proposed a facile method for the hydrophilic modification of waste rubber powder (HRP) and used it to reinforce a composite hydrogel. In the presence of toluene, dibenzoyl peroxide (BPO) diffused into the waste rubber powder. After the solvent was removed, BPO was adsorbed in the rubber powder, which was used to initiate the grafting polymerization of the acrylamide monomer on the rubber–water interface. As a result, the polyacrylamide (PAM) molecular chains were grafted onto the surface of the rubber powder to realize hydrophilic modification. The success of the grafting modification was confirmed by FTIR, contact angle testing, and thermogravimetric analysis. The hydrophilic modified waste rubber powder was used to reinforce the PAM hydrogel. Mechanical tests showed that the tensile strength and elongation at the break of the composite hydrogel reached 0.46 MPa and 1809%, respectively, which was much higher than those of pure PAM hydrogel. Such a phenomenon indicates that the waste rubber particles had a strengthening effect.