Ionic Liquids and Ionic Liquid Binary Mixtures as Electrolytes for Lithium Batteries

RSC Advances ◽  
2016 ◽  
Vol 6 (93) ◽  
pp. 90165-90171 ◽  
Author(s):  
Salvatore Marullo ◽  
Francesca D'Anna ◽  
Paola R. Campodonico ◽  
Renato Noto

We studied how mixing ionic liquids affected the rate of the Diels Alder reaction between 9-anthracenemethanol and N-ethylmaleimide.


Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6344
Author(s):  
Philipp S. Borchers ◽  
Patrick Gerlach ◽  
Yihan Liu ◽  
Martin D. Hager ◽  
Andrea Balducci ◽  
...  

In this work, two new redox-active ionic liquids, one based on 2,2,6,6-tetramethylpiperidine-N-oxide and the other based on 4,4′-bipyridine, are synthesized and characterized. A ferrocene-based redox-active ionic liquid is used for referencing the results. All ionic liquids are formed via salt-metathesis from halogenate to bis(trifluoromethylsulfonyl)imide. Their fundamental thermal characteristics are assessed with differential scanning calorimetry. While the imidazolium ionic liquids show no melting point, the phase transition is well observable for the viologen-based ionic liquid. The properties of the neat redox-active ionic liquids and of binary mixtures containing these ionic liquids (0.1 m) and 1-butyl-1-methyl pyrrolidinium-bis(trifluoromethylsulfonyl)imide have been investigated. Finally, the use of these binary mixtures in combination with activated carbon-based electrodes has been considered in view of the use of these redox-active electrolytes in supercapacitors.


2019 ◽  
Vol 64 (11) ◽  
pp. 4891-4903 ◽  
Author(s):  
Nicole S. M. Vieira ◽  
Isabel Vázquez-Fernández ◽  
João M. M. Araújo ◽  
Natalia V. Plechkova ◽  
Kenneth R. Seddon ◽  
...  

2007 ◽  
Vol 52 (6) ◽  
pp. 2542-2542 ◽  
Author(s):  
Paloma Navia ◽  
Jacobo Troncoso ◽  
Luis Romaní

2013 ◽  
Vol 675 ◽  
pp. 248-251
Author(s):  
Zhuo Li ◽  
Chang Ping Li

As a new environmentally friendly solvent, ionic liquids have been investigated widely. The lack of physico-chemical properties data of ionic liquids has become a bottleneck that restricts their applications. In this study, the investigation of the density for binary mixtures of CnpyNTf2 (n = 2, 4, 5) and methanol is measured using Westphal balance. This study would be very important for the application of binary mixtures of ionic liquid and methanol in developing new energy storage material.


2008 ◽  
Vol 37 (5) ◽  
pp. 677-688 ◽  
Author(s):  
Paloma Navia ◽  
Jacobo Troncoso ◽  
Luis Romaní

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