Platinum Nanowire-Based Highly Active and Durable Electrocatalyst for PEM Fuel Cells

2021 ◽  
Vol 14 (2) ◽  
pp. 1034-1041
Author(s):  
Jean-Pol Dodelet ◽  
Vassili Glibin ◽  
Gaixia Zhang ◽  
Ulrike I. Kramm ◽  
Régis Chenitz ◽  
...  

The fast decay in PEM fuel cells of a highly active, high performance, but unstable Fe/N/C catalyst like our NC_Ar + NH3 follows a chemical, not an electrochemical, demetallation mechanism for its ORR active FeN4 sites in the catalyst micropores.


2019 ◽  
Vol 12 (10) ◽  
pp. 3015-3037 ◽  
Author(s):  
Gaixia Zhang ◽  
Xiaohua Yang ◽  
Marc Dubois ◽  
Michael Herraiz ◽  
Régis Chenitz ◽  
...  

F2-Fluorination of Fe/N/C catalysts poisons FeN4, but not CNx sites. Main causes of instability in PEMFCs are either FeN4 demetalation for Fe/N/C or H2O2 when FeN4 sites are poisoned by fluorination or absent as in MOF_CNx_Ar + NH3.


2018 ◽  
Vol 11 (2) ◽  
pp. 365-382 ◽  
Author(s):  
Régis Chenitz ◽  
Ulrike I. Kramm ◽  
Michel Lefèvre ◽  
Vassili Glibin ◽  
Gaixia Zhang ◽  
...  

Micropores are largely responsible for Fe/N/C catalytic activity, but are also intrinsically responsible for the rapid initial performance loss in PEMFC.


2014 ◽  
Vol 20 (S3) ◽  
pp. 476-477
Author(s):  
Goran Dražić ◽  
Marjan Bele ◽  
Andraž Pavlišič ◽  
Primož Jovanovič ◽  
Milena Zorko ◽  
...  

2019 ◽  
Vol 11 (1) ◽  
pp. 241-247 ◽  
Author(s):  
Vijayadurga Nallathambi ◽  
Gang Wu ◽  
Nalini Subramanian ◽  
Swaminatha Kumaraguru ◽  
Jong-Won Lee ◽  
...  

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