First-Passage-Time Kinetic Monte Carlo Simulation of Nucleation and Growth in Electrodeposition

2011 ◽  
Vol 48 (3) ◽  
pp. 699-712 ◽  
Author(s):  
Tomoyuki Ichiba ◽  
Constantinos Kardaras

We propose a method for estimating first passage time densities of one-dimensional diffusions via Monte Carlo simulation. Our approach involves a representation of the first passage time density as the expectation of a functional of the three-dimensional Brownian bridge. As the latter process can be simulated exactly, our method leads to almost unbiased estimators. Furthermore, since the density is estimated directly, a convergence of order 1 / √N, where N is the sample size, is achieved, which is in sharp contrast to the slower nonparametric rates achieved by kernel smoothing of cumulative distribution functions.


2011 ◽  
Vol 48 (03) ◽  
pp. 699-712
Author(s):  
Tomoyuki Ichiba ◽  
Constantinos Kardaras

We propose a method for estimating first passage time densities of one-dimensional diffusions via Monte Carlo simulation. Our approach involves a representation of the first passage time density as the expectation of a functional of the three-dimensional Brownian bridge. As the latter process can be simulated exactly, our method leads to almost unbiased estimators. Furthermore, since the density is estimated directly, a convergence of order 1 / √N, where N is the sample size, is achieved, which is in sharp contrast to the slower nonparametric rates achieved by kernel smoothing of cumulative distribution functions.


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