Two-Color Two-Photon Ionization Spectrum of Pyrene in N-Hexane
Keyword(s):
The photoionization process of pyrene in non-polar solvent has been investigated using a two-color two-photon ionization technique. The ionization spectrum near threshold of pyrene in n-hexane was measured by a delayed irradiation of a dye laser 20 ns after an N2 laser at total excitation energies of 5.9–6.22 eV. The two-photon ionization threshold of pyrene was in the vicinity of 5.9 eV which is larger by 0.7 eV than that expected from the onset of one-photon ionization. The ionization spectrum shows maxima at 5.92 and 5.99 eV which may be assigned to an autoionization process.
2004 ◽
Vol 108
(32)
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pp. 12111-12115
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2011 ◽
Vol 9
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pp. 010203-10206
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1981 ◽
Vol 84
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pp. 248-252
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1982 ◽
Vol 31
(7)
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pp. E247-E250
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1978 ◽
Vol 33
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pp. 1546-1548
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