Temperature-Dependent Broadening of the Ultraviolet Photoelectron Spectrum of Au(110)

To determine the thermodynamic temperature of a solid surface from the electron energy distribution measured by photoelectron spectroscopy, it is necessary to accurately evaluate the energy broadening of the photoelectron spectrum and investigate its temperature dependence. Broadening functions in the photoelectron spectrum of Au(110)’s surface near the Fermi level were estimated successfully using the relationship between the Fourier transform and the convolution integral. The Fourier transform could simultaneously reduce the noise of the spectrum when the broadening function was derived. The derived function was in the form of a Gaussian, whose width depended on the thermodynamic temperature of the sample and became broader at higher temperatures. The results contribute to improve accuracy of the determination of thermodynamic temperature from the photoelectron spectrum and provide useful information on the temperature dependence of electron scattering in photoelectron emission processes.

Pump-Probe Delay Controlled by Laser-dressed Ionization with Isolated Attosecond Pulses

In a recent work [1], we demonstrated how laser-dressed ionization can be harnessed to control with attosecond accuracy the time delay between an extreme-ultraviolet (XUV) attosecond pulse train and an infrared (IR) femtosecond pulse. In this case, the comb-like photoelectron spectrum obtained by ionizing a gas target with the two superimposed beams exhibits peaks oscillating with the delay. Two of them can be found to oscillate in phase quadrature, allowing an optimal measurement and stabilization of the delay over a large range. Here we expand this technique to isolated attosecond pulses, by taking advantage of the delay-modulation of attosecond streaking traces. Although the photoelectron spectrum contains no peaks in that case, it is possible to reconstruct the pump-probe delay by simply monitoring the mean energy of the spectrum and the amplitude at this energy. In general, we find that active delay stabilization based on laser-dressed ionization is possible as long as the XUV pulses are chirped.

Quantum calculations of the photoelectron spectra of the OH−·NH3 anion: implications for OH + NH3 → H2O + NH2 reaction dynamics

Quantum dynamics calculations were performed to analyze the experimentally measured photoelectron spectrum of the OH−·NH3 anion complex.