Properties of Waterborne Polyurethane Adhesives: Effect of Chain Extender and Polyol Content

2009 ◽  
Vol 23 (1) ◽  
pp. 177-193 ◽  
Author(s):  
Mohammad Mizanur Rahman ◽  
Han-Do Kim ◽  
Won-Ki Lee
2009 ◽  
Vol 23 (15) ◽  
pp. 1953-1972 ◽  
Author(s):  
Elena Orgilés-Calpena ◽  
Francisca Arán-Aís ◽  
Ana M. Torró-Palau ◽  
César Orgilés-Barceló ◽  
José Miguel Martín-Martínez

Author(s):  
Mohammad Mizanur Rahman ◽  
Md. Hasan Zahir ◽  
Han Do Kim

A series of waterborne polyurethane (WBPU)/modified lignin amine (MLA) adhesives was prepared using modified lignin amine (MLA) as a chain extender by a prepolymer mixing process. A successful Mannich reaction was achieved during the synthesis of MLA by reacting lignin with bis(3-aminopropyl)amine. Higher tensile strength, Young’s modulus and thermal stability were recorded for WBPU/MLA adhesives with higher MLA contents. The WBPU/MLA adhesive materials were used to coat PVC substrates. The adhesive strength increased with increasing MLA content. More importantly, the MLA also enhanced the WBPU/MLA coating in terms of adhesive strength at moderately high temperatures as well as under natural weather exposed conditions. The adhesive strength was essentially unaffected with 6.48 mole% MLA in the WBPU/MLA coating after exposure to natural weather conditions for 180 days.


2014 ◽  
Vol 90 (5-6) ◽  
pp. 437-456 ◽  
Author(s):  
M. A. Pérez-Limiñana ◽  
F. Arán-Aís ◽  
C. Orgilés-Barceló

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