A Study on the Manufacture and Physical Properties of Liquid Adhesive for Wood Preservation - Focusing on the Synthesis of Gelatin and Carrageenan -

In order to improve the usability of glue, a traditional adhesive material, and the gelation process of seaweed extract carrageenan, a liquid adhesive for wood preservation was prepared by mixing the two materials. The prepared wood adhesive was mixed with a 15 wt% aqueous solution of glue, λ-carrageenan, an antibacterial agent, an antifoaming agent, and the maximum adhesive strength of 1.80 Mpa was confirmed. As a result of comparison, the adhesive strength was superior to that of 5 different types of traditional natural adhesive ingredients (aqueous solution) and 1 type of polyvinyl acetate-based adhesive.

Effect of the Stress State on the Adhesive Strength of an Epoxy-Bonded Assembly

The paper studies the adhesive strength of aluminum alloy specimens bonded with the use of an epoxy adhesive, under the tensile-shear stress state, depending on the testing temperature. Tension of modified Arcan specimens with load angles of 0, 22.5, 45, 67.5, and 90° with respect to the plane of adhesion is chosen as the experimental method. Experiments were performed at temperatures of −50, +23, and +50 °С. The analysis of the obtained results yields a linear fracture criterion and a fracture locus for the adhesive failure strain energy density, which takes into account the ratio of the elastic properties of the adhesive to those of the substrate. The region bounded by the fracture loci of adhesive strength and ultimate strain energy density determines the conditions for the safe loading of the bonded assembly in terms of the energy and force criteria of adhesive failure. The proposed fracture loci can be used, preferably simultaneously, to estimate the in-service strength and reliability of adhesively bonded assemblies.

STRENGTH OF MULTILAYER POLYMER PIPE TAKING INTO ACCOUNT CHANGE IN PHYSICAL AND MECHANICAL PROPERTIES OF THE MATERIAL

Strength if a multilayer polymer pipe under the action of the system if external loads is studied taking into account the change in physical and mechanical properties of the material. Mechanical effect, the dependence of joint deformability of several polymer materials on the character of change if their physical and chemical properties was established. Occurrence and dependence of physical and chemical properties of the material and also breaking stresses between the layer determining adhesive strength of layered polymer pipe was established.

Simulation and Experimental Study on the Ultrasonic Micro-Vibration De-Icing Method for Wind Turbine Blades

In cold and humid regions, ice accretion sometimes develops on the blades of wind turbines. Blade icing reduces the power generation of the wind turbine and affects the safe operation of the wind farm. For this paper, ultrasonic micro-vibration was researched as an effective de-icing method to remove ice from the wind turbine blade surface and improve the efficiency of wind turbine power generation. A blade segment with NACA0018 airfoil and the hollow structure at the leading edge was designed. The modal analysis of the blade was simulated by ANSYS, and the de-icing vibration mode was selected. Based on the simulation results, the blade segment sample with PZT patches was machined, and its natural frequencies were measured with an impedance analyzer. A return-flow icing wind tunnel system, and a device used to measure the adhesive strength of ice covering the airfoil blade, were designed and manufactured. The experiments on the adhesive strength of the ice were carried out under the excitation of the ultrasonic vibration. The experimental results show that the adhesive strength of the ice, which was generated under the dynamic flow field condition, was lower than the ice generated by water under the static flow field condition. Under the excitation of the ultrasonic vibration, the adhesive strength of the ice decreased. When the excitation frequency was 21.228 kHz, the adhesive strength was the lowest, which was 0.084 MPa. These research findings lay the theoretical and experimental foundations for researching in-depth the application of the ultrasonic de-icing technology to wind turbines.

Geopolymer mortars based on natural zeolite

Geopolymers based on Bulgarian natural zeolite (clinoptilolite) were synthesized using alkaline activators in order to prepare plaster/render mortar. The influence of the alkali concentrations of the activator solution was examined in regard to tensile strength and adhesion to concrete. Microstructure of the obtained geopolymer pastes was analysed by XRD, FTIR, SEM. The results showed adhesive strength to concrete up to 3.6 MPa and tensile strength up to 5.44 MPa. The present study shows a promising potential of the geopolymers as coating material for concrete.

Temporal Evolution of Pressure Generated by a Nanosecond Laser Pulse Used for Assessment of Adhesive Strength of the Tungsten–Zirconium–Borides Coatings

The article presents theoretical and experimental study of shock waves induced by a nanosecond laser pulse. Generation of surface plasma pressure by ablation of the graphite absorption layer in water medium and shock wave formation were analyzed theoretically and experimentally. The amplitude and temporal variation of the shock wave pressure was determined basing on a proposed hydrodynamic model of nanosecond laser ablation and experimentally verified with use of a polyvinylidene fluoride (PVDF) piezoelectric-film sensor. The determined pressure wave was used for examination of adhesive strength of tungsten–zirconium–boride coatings on steel substrate. The magnetron sputtered (MS) W–Zr–B coatings show good adhesion to the steel substrate. The obtained experimental results prove the correctness of the proposed model as well as the suitability of the procedure for assessment of adhesive strength.

Lignosulfonate-Based Polyurethane Adhesives

The feasibility of using lignosulfonate (LS) from acid sulphite pulping of eucalyptus wood as an unmodified polyol in the formulation of polyurethane (PU) adhesives was evaluated. Purified LS was dissolved in water to simulate its concentration in sulphite spent liquor and then reacted with 4,4′-diphenylmethane diisocyanate (pMDI) in the presence or absence of poly(ethylene glycol) with Mw 200 (PEG200) as soft crosslinking segment. The ensuing LS-based PU adhesives were characterized by infrared spectroscopy and thermal analysis techniques. The adhesion strength of new adhesives was assessed using Automated Bonding Evaluation System (ABES) employing wood strips as a testing material. The results showed that the addition of PEG200 contributed positively both to the homogenization of the reaction mixture and better crosslinking of the polymeric network, as well as to the interface interactions and adhesive strength. The latter was comparable to the adhesive strength recorded for a commercial white glue with shear stress values of almost 3 MPa. The optimized LS-based PU adhesive formulation was examined for the curing kinetics following the Kissinger and the Ozawa methods by non-isothermal differential scanning calorimetry, which revealed the curing activation energy of about 70 kJ·mol−1.