Development of an Impedance Meter Based on a Digital Lock-In Amplifier with 4-Kelvin-Probe Electrodes

2021 ◽  
Vol 18 (4) ◽  
pp. 1171-1176
Author(s):  
Rafael da Silva Ferraz ◽  
Raiff Sales da Fonseca ◽  
Cláudio Bastos da Silva ◽  
Horácio Tertuliano Santos Filho

In this paper, it is described a new design of a digital Lock-In amplifier applied to 4-Kelvin- probe electrodes for the measurement of complex electrical variables. The proposed design is based on the operation of a Phase Sensitive Detection (PSD) circuit and on signal acquisition by the Nyquist principle. The hardware basically consists of a programmable embedded system and an analog interfacing circuit. The microcontroller within the circuit was programmed using standard C language for portability and performs the acquisition of the resulting signal along with mathematical operations. Experimental tests on the prototype have shown that it performs as theoretically predicted.

1989 ◽  
Vol 60 (7) ◽  
pp. 2257-2259 ◽  
Author(s):  
S. Carrato ◽  
G. Paolucci ◽  
R. Tommasini ◽  
R. Rosei

Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 601
Author(s):  
Felix Hemmingsson ◽  
Andreas Schaefer ◽  
Magnus Skoglundh ◽  
Per-Anders Carlsson

Methane is a well-established fuel molecule whose production from CO 2 through methanation garners increasing interest as an energy storage solution. While often produced with Ni based catalysts, other metals are of interest thanks to higher robustness and activity-selectivity numbers. The Rh/CeO 2 catalyst has shown appreciable properties for CO 2 methanation and its structural dynamics has been studied in situ. However, the reaction pathway is unknown. Here, we present infrared modulation excitation spectroscopy measurements with phase sensitive detection of a Rh/CeO 2 catalyst adsorbate composition during H 2 pulsing (0–2 vol.%) to a constant CO 2 (0.5 vol.%) feed. Various carbonyl (CO) and carbonate (b-CO 3 /p-CO 3 ) ad-species clearly respond to the hydrogen stimulus, making them potential reaction intermediates. The different CO ad-species are likely intermediates for product CO and CH 4 but their individual contributions to the respective formations are not unambiguously ascertained. As for the carbonate dynamics, it might be linked to the reduction/oxidation of the CeO 2 surface upon H 2 pulsing. Formate (HCOO) ad-species are clearly visible but appear to be, if not spectators, linked to slow side reactions possibly also affected by CeO 2 redox processes.


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