scholarly journals Nickel-catalyzed carbonylation of thioacetates with aryl iodides via CO insertion and C–S bond cleavage

2021 ◽  
pp. 174751982110281
Author(s):  
Wen-Peng Mai ◽  
Hong-Da Sui ◽  
Ming-Xiu Lv ◽  
Kui Lu

Aryl thioesters are synthesized via nickel-catalyzed carbonylation of thioacetates with aryl iodides. Alkyl thioacetates undergo coupling with carbon monoxide and aryl iodides to produce the desired aryl thioesters in moderate yields. This catalytic carbonylative coupling process provides a cost-effective and direct approach for the preparation of useful thioesters.

2017 ◽  
Vol 129 (39) ◽  
pp. 12102-12106 ◽  
Author(s):  
Jianzhong Liu ◽  
Xiaojin Wen ◽  
Chong Qin ◽  
Xinyao Li ◽  
Xiao Luo ◽  
...  

2021 ◽  
Author(s):  
Clemens Krempner ◽  
Chamila Manankandayalage ◽  
Daniel K Unruh

Utilizing an intramolecular frustrated Lewis pair (FLP) decorated with a strongly donating guanidino moiety enabled the formation of a thermally remarkably stable FLP-CO adduct, which at 120°C underwent CO migration...


2011 ◽  
Vol 123 (52) ◽  
pp. 12803-12807 ◽  
Author(s):  
Chong Qin ◽  
Wang Zhou ◽  
Feng Chen ◽  
Yang Ou ◽  
Ning Jiao

ChemInform ◽  
2003 ◽  
Vol 34 (24) ◽  
Author(s):  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Federica Gavazza ◽  
Antonella Goggiamani

2021 ◽  
Vol 21 (8) ◽  
pp. 4400-4405
Author(s):  
Junyeop Lee ◽  
Nam Gon Do ◽  
Dong Hyuk Jeong ◽  
Sae-Wan Kim ◽  
Maeum Han ◽  
...  

Carbon monoxide (CO) is an odorless, colorless, tasteless, extremely flammable, and highly toxic gas. It is produced when there is insufficient oxygen supply during the combustion of carbon to produce carbon dioxide (CO2). CO is produced from operating engines, stoves, or furnaces. CO poisoning occurs when CO accumulates in the bloodstream and can result in severe tissue damage or even death. Many types of CO sensors have been reported, including electrochemical, semiconductor metal-oxide, catalytic combustion, thermal conductivity, and infrared absorption-type for the detection of CO. However, despite their excellent selectivity and sensitivity, issues such as complexity, power consumption, and calibration limit their applications. In this study, a fabricbased colorimetric CO sensor is proposed to address these issues. Potassium disulfitopalladate (II) (K2Pd(SO3)2) is dyed on a polyester fabric as a sensing material for selective CO detection. The sensing characteristics and performance are investigated using optical instruments such as RGB sensor and spectrometer. The sensor shows immediate color change when exposed to CO at a concentration that is even lower than 20 ppm before 2 min. The fast response time of the sensor is attributed to its high porosity to react with CO. This easy-to-fabricate and cost-effective sensor can detect and prevent the leakage of CO simultaneously with high sensitivity and selectivity toward CO.


2020 ◽  
Vol 59 (12) ◽  
pp. 4897-4901 ◽  
Author(s):  
Andreas Heilmann ◽  
Jamie Hicks ◽  
Petra Vasko ◽  
Jose M. Goicoechea ◽  
Simon Aldridge

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