scholarly journals Silent Discharge Reactions in Aqueous Solutions. VII. Alkaline Aqueous Solution of Potassium Ferricyanide in Atmospheres of Helium and Argon

1967 ◽  
Vol 40 (11) ◽  
pp. 2507-2511 ◽  
Author(s):  
Akira Yokohata ◽  
Satoru Tsuda
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Potassium Ferricyanide ◽  
Silent Discharge ◽  
Alkaline Aqueous Solution

scholarly journals XV.—The Viscosity of Solutions

1907 ◽  
Vol 45 (2) ◽  
pp. 397-406 ◽  
Author(s):  
C. Ranken ◽  
W. W. Taylor
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Potassium Chloride ◽  
Mercuric Chloride ◽  
Potassium Ferricyanide ◽  
Potassium Ferrocyanide ◽  
Potassium Chlorate ◽  
Ammonium Iodide ◽  
Other Substances ◽  
Negative Viscosity

In a recent paper published by the authors, some measurements of the viscosity of aqueous solutions indicated that it would be of interest to investigate more fully the viscosity of solutions, especially those which exhibit what is now generally known as “negative viscosity,” over a wider range of temperature.This has now been done to a certain extent, and to enable a comparison to be made between electrolytes and non-electrolytes in aqueous solution, some other substances have been included in the investigation. They are:—potassium chloride, potassium chlorate, ammonium iodide, potassium ferricyanide, potassium ferrocyanide; mercuric chloride, mercuric cyanide; carbamide.

The oxidation of ortho-anisidine in alkaline medium. A product characterization and an EPR study

1994 ◽  
Vol 72 (5) ◽  
pp. 1351-1356 ◽  
Author(s):  
Adele Bolognese ◽  
Marina Buonanno ◽  
Antonio Cantilena ◽  
Giovanni Musci ◽  
Angelo Alberti
Keyword(s):  
Aqueous Solution ◽  
Alkaline Medium ◽  
Potassium Ferricyanide ◽  
Azo Compounds ◽  
Radical Mechanism ◽  
Radical Species ◽  
Alkaline Aqueous Solution ◽  
Product Characterization ◽  
Alkaline Oxidation

Alkaline oxidation of ortho-anisidine by potassium ferricyanide in alkaline aqueous solution was examined. Azo compounds, a diamine, and para-iminoquinones were isolated from the highly coloured reaction mixture. The reaction was also carried out within the cavity of an EPR spectrometer and two radical species have been detected. Following these product results and EPR studies, a radical mechanism is proposed for the process.

scholarly journals Speciation and structure of tin(ii) in hyper-alkaline aqueous solution

2014 ◽  
Vol 43 (48) ◽  
pp. 17971-17979 ◽  
Author(s):  
Éva G. Bajnóczi ◽  
Eszter Czeglédi ◽  
Ernő Kuzmann ◽  
Zoltán Homonnay ◽  
Szabolcs Bálint ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Alkaline Aqueous Solution

In hyper-alkaline aqueous solutions, the three-legged stool-like [Sn(OH)3]− is the only hydroxido complex with a very short (2.078 Å) Sn–O distance.

scholarly journals Speciation and the structure of lead(ii) in hyper-alkaline aqueous solution

2014 ◽  
Vol 43 (46) ◽  
pp. 17539-17543 ◽  
Author(s):  
Éva G. Bajnóczi ◽  
István Pálinkó ◽  
Tamás Körtvélyesi ◽  
Szabolcs Bálint ◽  
Imre Bakó ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Alkaline Aqueous Solution

In hyper-alkaline aqueous solutions, lead(ii) is present exclusively as [Pb(OH)3]−. Other species, like [Pb(OH)4]2−, [PbOOH]−or [PbO2]2−are not detectable.

Effect of thermal history of aqueous solutions of KCl on the metastable zone width

1984 ◽  
Vol 49 (3) ◽  
pp. 559-569 ◽  
Author(s):  
Jaroslav Nývlt
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Thermal History ◽  
Equilibrium Solubility ◽  
Metastable Zone Width ◽  
Zone Width ◽  
Preceding Experiment ◽  
History Of ◽  
Metastable Zone ◽  
The Given

The metastable zone width of an aqueous solution of KCI was measured as a function of the time and temperature of overheating above the equilibrium solubility temperature. It has been found that when the experiments follow close upon one another, the parameters of the preceding experiment affect the results of the experiment to follow.The results are interpreted in terms of hypotheses advanced in the literature to account for the effect of thermal history of solution. The plausibility and applicability of these hypotheses are assessed for the given cause of aqueous solution of a well soluble electrolyte.

scholarly journals I. Thermo-electric behaviour of aqueous solutions with mercurial electrodes

1879 ◽  
Vol 29 (196-199) ◽  
pp. 472-482 ◽  
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Internal Diameter ◽  
Thermo Electric ◽  
Thin Glass ◽  
Mercury Surface

In order to investigate this subject, I devised and constructed the following apparatus :—A and B are two thin glass basins, 81 millims. internal diameter (= 5,153 sq. millims. of mercury surface), and 6·0 centims. deep; each containing a layer of mercury about 1·0 centim. deep, covered by a layer, about 3 centims. deep, of the aqueous solution to be examined.

scholarly journals Meta-studtite stability in aqueous solutions. Impact of HCO3−, H2O2 and ionizing radiation on dissolution and speciation

2021 ◽  
Author(s):  
Junyi Li ◽  
Zoltán Szabó ◽  
Mats Jonsson
Keyword(s):  
Aqueous Solution ◽  
Ionizing Radiation ◽  
Aqueous Solutions ◽  
Carbonate Complexes ◽  
C Nmr

Four different uranyl-(peroxide)-carbonate complexes were identified during studtite and meta-studtite dissolution in aqueous solution containing 10 mM HCO3− by 13C NMR.

Sign in / Sign up

Export Citation Format

Share Document