A CONVENIENT SYNTHESIS OF KETOXIMES FROM GRIGNARD REAGENTS AND NITRO COMPOUNDS ACTIVATED BYN,N-DIMETHYLCHLOROMETHYLENIMINIUM CHLORIDE

Chemistry Letters ◽

10.1246/cl.1983.1537 ◽

1983 ◽

Vol 12 (10) ◽

pp. 1537-1540 ◽

Author(s):

Tamotsu Fujisawa ◽

Yoshitsugu Kurita ◽

Toshio Sato

Keyword(s):

Nitro Compounds ◽

Grignard Reagents ◽

Convenient Synthesis

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ChemInform Abstract: A CONVENIENT SYNTHESIS OF KETOXIMES FROM GRIGNARD REAGENTS AND NITRO COMPOUNDS ACTIVATED BY N,N-DIMETHYLCHLOROMETHYLENIMINIUM CHLORIDE

Chemischer Informationsdienst ◽

10.1002/chin.198420151 ◽

1984 ◽

Vol 15 (20) ◽

Author(s):

T. FUJISAWA ◽

Y. KURITA ◽

T. SATO

Keyword(s):

Nitro Compounds ◽

Grignard Reagents ◽

Convenient Synthesis

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ChemInform Abstract: IRON CATALYZED CROSS-COUPLING REACTIONS OF ACYL CHLORIDES WITH GRIGNARD REAGENTS. A MILD, GENERAL, AND CONVENIENT SYNTHESIS OF ALIPHATIC AND AROMATIC KETONES

Chemischer Informationsdienst ◽

10.1002/chin.198507141 ◽

1985 ◽

Vol 16 (7) ◽

Author(s):

V. FIANDANESE ◽

G. MARCHESE ◽

V. MARTINA ◽

L. RONZINI

Keyword(s):

Cross Coupling ◽

Grignard Reagents ◽

Coupling Reactions ◽

Aromatic Ketones ◽

Acyl Chlorides ◽

Cross Coupling Reactions ◽

Convenient Synthesis

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Metalation of α-diazocarbonyl compounds using Grignard reagents. A convenient synthesis of α-diazo-β-ketoesters and mixed esters of α-diazomalonate

Tetrahedron Letters ◽

10.1016/j.tetlet.2004.01.074 ◽

2004 ◽

Vol 45 (11) ◽

pp. 2417-2419 ◽

Author(s):

Erick Cuevas-Yañez ◽

Joseph M. Muchowski ◽

Raymundo Cruz-Almanza

Keyword(s):

Grignard Reagents ◽

Convenient Synthesis

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ChemInform Abstract: N-Allylhydroxylamines from 1,2-Addition of Allyl Grignard Reagents to Nitro Compounds: Generality and Drawbacks of the Reaction.

10.1002/chin.199044129 ◽

1990 ◽

Vol 21 (44) ◽

Author(s):

L. BARBONI ◽

G. BARTOLI ◽

E. MARCANTONI ◽

M. PETRINI ◽

R. DALPOZZO

Keyword(s):

Nitro Compounds ◽

Grignard Reagents

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A Convenient Synthesis of 1,3-Dithiane Derivatives by Reaction of 4-Methyl-1,3-dithiane-2-thione with Grignard Reagents and Butyllithium

Chemistry Letters ◽

10.1246/cl.1991.1315 ◽

1991 ◽

Vol 20 (8) ◽

pp. 1315-1318 ◽

Author(s):

Akira Sugawara ◽

Ryuichi Sugawara ◽

Hirokazu Ito ◽

Hiroshi Tanaka ◽

Toru Segawa ◽

...

Keyword(s):

Grignard Reagents ◽

Convenient Synthesis

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ChemInform Abstract: A CONVENIENT SYNTHESIS OF 1-ALKYNES FROM METHOXYALLENE AND GRIGNARD REAGENTS IN THE PRESENCE OF COPPER(I) HALIDES

Chemischer Informationsdienst ◽

10.1002/chin.197445183 ◽

1974 ◽

Vol 5 (45) ◽

Author(s):

J. MEIJER ◽

P. VERMEER

Keyword(s):

Grignard Reagents ◽

Convenient Synthesis

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Three-component coupling of acetylenic sulfones, Grignard reagents and α, β-unsaturated carbonyls: A convenient synthesis of diallylic alcohols

Journal of Organometallic Chemistry ◽

10.1016/j.jorganchem.2016.10.026 ◽

2016 ◽

Vol 825-826 ◽

pp. 75-82 ◽

Author(s):

Changqing Liu ◽

Chao Zha ◽

Jing Jia ◽

Jian Fan ◽

Zhenda Liang ◽

...

Keyword(s):

Grignard Reagents ◽

Convenient Synthesis ◽

Unsaturated Carbonyls ◽

Three Component Coupling ◽

Acetylenic Sulfones

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289. Aliphatic nitro-compounds. Part X. Action of grignard reagents on the α-nitro-olefins

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9470001494 ◽

1947 ◽

Vol 0 (0) ◽

pp. 1494-1497 ◽

Author(s):

G. D. Buckley

Keyword(s):

Nitro Compounds ◽

Grignard Reagents ◽

Aliphatic Nitro Compounds

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ChemInform Abstract: Nitrones from Addition of Benzyl and Allyl Grignard Reagents to Alkyl Nitro Compounds: Chemo-, Regio-, and Stereoselectivity of the Reaction.

10.1002/chin.199309048 ◽

2010 ◽

Vol 24 (9) ◽

pp. no-no

Author(s):

G. BARTOLI ◽

E. MARCANTONI ◽

M. PETRINI

Keyword(s):

Nitro Compounds ◽

Grignard Reagents

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Synthesis of Chiral N-Nitro-oxazolidin-2-ones and O-(β-Nitraminoalkyl) Carbamates in Liquefied 1,1,1,2-Tetrafluoroethane Medium

Synthesis ◽

10.1055/s-0040-1706762 ◽

2020 ◽

Vol 52 (22) ◽

pp. 3485-3491

Author(s):

Sergei G. Zlotin ◽

Svetlana S. Arabadzhi ◽

Mikhail N. Zharkov ◽

Ilya V. Kuchurov

Keyword(s):

Nitro Compounds ◽

Hek293 Cells ◽

Human Embryonic Kidney ◽

Enantiomerically Pure ◽

Dinitrogen Pentoxide ◽

Convenient Synthesis ◽

Stereogenic Centers

AbstractA convenient synthesis of chiral N-nitro-oxazolidin-2-ones by nitration of α-amino acid derived 1,3-oxazolidin-2-ones containing one or two stereogenic centers with dinitrogen pentoxide in liquefied 1,1,1,2-tetrafluoroethane medium has been developed. The obtained N-nitroheterocycles were converted into enantiomerically pure O-(β-nitraminoalkyl) carbamates by treatment with ammonia or amines in the same solvent. The synthesized N-nitro compounds are slightly toxic in vitro to Human Embryonic Kidney 293 (HEK293) cells.

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