A Convenient Synthesis of 1,3-Dithiane Derivatives by Reaction of 4-Methyl-1,3-dithiane-2-thione with Grignard Reagents and Butyllithium

1991 ◽  
Vol 20 (8) ◽  
pp. 1315-1318 ◽  
Author(s):  
Akira Sugawara ◽  
Ryuichi Sugawara ◽  
Hirokazu Ito ◽  
Hiroshi Tanaka ◽  
Toru Segawa ◽  
...  
Keyword(s):  
Grignard Reagents ◽  
Convenient Synthesis

scholarly journals Stepwise Introduction of Different Substituents to α-Chloro-ω-hydrooligosilanes: Convenient Synthesis of Unsymmetrically Substituted Oligosilanes

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 99 ◽  
Author(s):  
Ken-ichiro Kanno ◽  
Yumi Aikawa ◽  
Yuka Niwayama ◽  
Misaki Ino ◽  
Kento Kawamura ◽  
...  
Keyword(s):  
Grignard Reagents ◽  
Convenient Synthesis

A series of unsymmetrically substituted oligosilanes were synthesized via stepwise introduction of different substituents to α-chloro-ω-hydrooligosilanes. The reactions of α-chloro-ω-hydrooligosilanes with organolithium or Grignard reagents gave hydrooligosilanes having various alkyl, alkenyl, alkynyl and aryl groups. Thus-obtained hydrooligosilanes were converted into alkoxyoligosilanes by ruthenium-catalyzed dehydrogenative alkoxylation with alcohols.

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