Three-component coupling of acetylenic sulfones, Grignard reagents and α, β-unsaturated carbonyls: A convenient synthesis of diallylic alcohols

2016 ◽  
Vol 825-826 ◽  
pp. 75-82 ◽  
Author(s):  
Changqing Liu ◽  
Chao Zha ◽  
Jing Jia ◽  
Jian Fan ◽  
Zhenda Liang ◽  
...  
Keyword(s):  
Grignard Reagents ◽  
Convenient Synthesis ◽  
Unsaturated Carbonyls ◽  
Three Component Coupling ◽  
Acetylenic Sulfones

A Convenient Synthesis of 1,3-Dithiane Derivatives by Reaction of 4-Methyl-1,3-dithiane-2-thione with Grignard Reagents and Butyllithium

1991 ◽  
Vol 20 (8) ◽  
pp. 1315-1318 ◽  
Author(s):  
Akira Sugawara ◽  
Ryuichi Sugawara ◽  
Hirokazu Ito ◽  
Hiroshi Tanaka ◽  
Toru Segawa ◽  
...  
Keyword(s):  
Grignard Reagents ◽  
Convenient Synthesis

Synthesis of C,N,N-Cyclometalated Gold(III) Complexes with Anionic Amide Ligands

Synlett ◽  
2021 ◽  
Author(s):  
Ryotaro Niizeki ◽  
Kosuke Higashida ◽  
Emna Mejri ◽  
Masaya Sawamura ◽  
Yohei Shimizu
Keyword(s):  
Electronic Properties ◽  
Synthesis Method ◽  
Amide Ligands ◽  
Convenient Synthesis ◽  
Benzamide Derivatives ◽  
Three Component Coupling

A series of neutral C,N,N Au(III) complexes was synthesized with N-(8-quinolinyl)benzamide derivatives and chiral N-(2-(oxazolin-2-yl)phenyl)benzamide derivatives. This convenient synthesis method for amide ligands as well as an operationally simple complexation by direct C-H auration permitted changes to both the steric and electronic properties of the Au(III) complexes for promoting catalytic three-component coupling of an aldehyde, an amine, and an alkyne.

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