Hairy Particles Synthesized by Living Anionic Polymerization-Induced Self-Assembly and Evaluation of Their Nanostructure

2021 ◽  
Author(s):  
Toshiki Terao ◽  
Hibiki Shiraishi ◽  
Mikito Yamazaki ◽  
Teruaki Hayakawa ◽  
Noboru Ohta ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Self Assembly ◽  
Living Anionic Polymerization

Controlled Synthesis and Ceramization of Well-Defined Fe/Si/C Ceramic Precursors by Living Anionic Polymerization

2016 ◽  
Vol 852 ◽  
pp. 579-584
Author(s):  
Qian Ce Zhang ◽  
Yan Zi Gou ◽  
Yi Fei Wang ◽  
Teng Fei Mao ◽  
Nan Wu ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Self Assembly ◽  
Controlled Synthesis ◽  
Living Anionic Polymerization ◽  
Elemental Compositions ◽  
Molecular Weights ◽  
Ceramic Precursors ◽  
Ft Ir ◽  
Weight Structure ◽  
Controllable Preparation

Two kinds of iron-containing ceramic precursors, PFS and PS-b-PFS, were synthesized via living anionic polymerization by using ferrocenyldimethylsilane and styrene as the monomers. The structures, elemental compositions and molecular weights were characterized by FT-IR, NMR, EDS and GPC, respectively. The homopolymerization of ferrocenyldimethylsilane was simulated using computational chemistry method. The copolymerization between ferrocenyldimethylsilane and styrene was investigated by altering the ratio between monomers and initiator (n-butyllithium). The experimental results indicated that the Mn, Mw and PDi of homopolymer PFS were 6.91×103 g/mol, 8.29×103 g/mol and 1.20, respectively. Moreover, the molecular weight, structure and composition of block copolymers PS-b-PFS, were successfully controlled by changing the ratio of styrene, n-butyllithium and ferrocenyldimethylsilane. Subsequently, using such iron-containing polymers as precursors, Fe/Si/C ceramics were obtained after sintering at 1400°C. The microstructures, morphologies and elemental compositions of ceramics were characterized by SEM and EDS. The results implied the controllable preparation of spherical Fe/Si/C ceramics was achieved via the self-assembly of precursors.

A polymerization-induced self-assembly process for all-styrenic nano-objects using the living anionic polymerization mechanism

2020 ◽  
Vol 11 (15) ◽  
pp. 2635-2639 ◽  
Author(s):  
Chengcheng Zhou ◽  
Jian Wang ◽  
Peng Zhou ◽  
Guowei Wang
Keyword(s):  
Diblock Copolymer ◽  
Anionic Polymerization ◽  
Self Assembly ◽  
Assembly Process ◽  
Living Anionic Polymerization ◽  
Polymerization Mechanism ◽  
Copolymer Poly

By combination of the living anionic polymerization (LAP) mechanism with the polymerization-induced self-assembly (PISA) technique, the all-styrenic diblock copolymer poly(p-tert-butylstyrene)-b-polystyrene (PtBS-b-PS) based LAP PISA was successfully developed.

Living Anionic Polymerization of 4-Halostyrenes

2021 ◽  
Vol 54 (3) ◽  
pp. 1489-1498
Author(s):  
Raita Goseki ◽  
Taro Koizumi ◽  
Reina Kurakake ◽  
Satoshi Uchida ◽  
Takashi Ishizone
Keyword(s):  
Anionic Polymerization ◽  
Living Anionic Polymerization

Precise Synthesis of Novel Ferrocene-Based Star-Branched Polymers by Using Specially Designed 1,1-Diphenylethylene Derivatives in Conjunction with Living Anionic Polymerization

2010 ◽  
Vol 20 (3) ◽  
pp. 445-456 ◽  
Author(s):  
Tomoyuki Hirano ◽  
Hee-Soo Yoo ◽  
Yohko Ozama ◽  
Ahmed Abou El-Magd ◽  
Kenji Sugiyama ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Branched Polymers ◽  
Living Anionic Polymerization

Living Anionic Polymerization ofN-Methacryloyl-2-methylaziridine

2009 ◽  
Vol 279 (1) ◽  
pp. 21-28 ◽  
Author(s):  
Takashi Ishizone ◽  
Jun-ichi Kusakabe ◽  
Takashi Suzuki
Keyword(s):  
Anionic Polymerization ◽  
Living Anionic Polymerization

Synthesis of a sequence-controlled in-chain alkynyl/tertiary amino dual-functionalized terpolymer via living anionic polymerization

2018 ◽  
Vol 9 (1) ◽  
pp. 108-120 ◽  
Author(s):  
Lincan Yang ◽  
Hongwei Ma ◽  
Li Han ◽  
Xinyu Hao ◽  
Pibo Liu ◽  
...  
Keyword(s):  
Anionic Polymerization ◽  
Kinetic Characteristics ◽  
Living Anionic Polymerization ◽  
Sequence Structure ◽  
H Nmr ◽  
Nmr Method ◽  
Tertiary Amino

A dual-functionalized sequence-defined terpolymer was synthesized via living anionic polymerization; meanwhile its kinetic characteristics and sequence structure were investigated in detail via the in situ1H NMR method.

Sign in / Sign up

Export Citation Format

Share Document