scholarly journals Precision Polymerization and Polymers II. Living Radical Polymerization with Transition Metal Complexes.

1997 ◽  
Vol 54 (12) ◽  
pp. 875-885 ◽  
Author(s):  
Mitsuo SAWAMOTO ◽  
Masami KAMIGAITO
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Radical Polymerization ◽  
Transition Metal Complexes ◽  
Living Radical Polymerization

Catalytic Chain Transfer Polymerization: an Overview

2002 ◽  
Vol 55 (7) ◽  
pp. 381 ◽  
Author(s):  
J. P. A. Heuts ◽  
G. E. Roberts ◽  
J. D. Biasutti
Keyword(s):  
Free Radical ◽  
Transition Metal ◽  
Metal Complexes ◽  
Radical Polymerization ◽  
Transition Metal Complexes ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Catalytic Chain Transfer ◽  
Mechanistic Understanding ◽  
Chain Transfer Polymerization

Catalytic chain transfer polymerization is a very efficient and versatile free-radical polymerization technique for the synthesis of functional macromonomers. The process is based on the ability of certain transition metal complexes, most notably of low-spin CoII complexes such as cobaloximes, to catalyse the chain transfer to monomer reaction. A brief overview is given of the applications and the mechanistic understanding of catalytic chain transfer polymerization.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

Density Functional Calculations of EPR Parameter g Tensors of Some Transition Metal Complexes

2011 ◽  
Vol 2 (2) ◽  
pp. 139-141
Author(s):  
Vinita Prajapati ◽  
◽  
P.L.Verma P.L.Verma ◽  
Dhirendra Prajapati ◽  
B.K.Gupta B.K.Gupta
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Density Functional Calculations ◽  
Density Functional
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