Chemical corrosion of molybdenum electrode in a molten basalt environment

2015 ◽  
Vol 56 (5) ◽  
pp. 212-216
Author(s):  
Jianxun Liu ◽  
◽  
Liang Lei ◽  
Changhai Peng ◽  
Ming Jiang ◽  
...  
Keyword(s):  
Chemical Corrosion ◽  
Molybdenum Electrode

INCONEL X

Alloy Digest ◽  
1953 ◽  
Vol 2 (3) ◽  
Keyword(s):  
High Temperature ◽  
Base Alloy ◽  
High Strength ◽  
Heat Treating ◽  
Age Hardening ◽  
Chemical Corrosion ◽  
International Nickel Company ◽  
Temperature Performance ◽  
Nickel Base ◽  
Corrosion And Oxidation

Abstract INCONEL X is a high-strength, high-temperature nickel-base alloy responding to age hardening for maximum properties. It is highly resistant to chemical corrosion and oxidation. Its creep rate is low under high stresses at 1200-1500 F. This datasheet provides information on composition, physical properties, hardness, elasticity, and tensile properties as well as fracture toughness, creep, and fatigue. It also includes information on high temperature performance as well as heat treating, machining, joining, and surface treatment. Filing Code: Ni-3. Producer or source: International Nickel Company Inc..

Studies on Cerium Electrochemistry in High Temperature Ionic Liquids

2018 ◽  
Vol 69 (1) ◽  
pp. 112-115
Author(s):  
Ana Maria Popescu ◽  
Virgil Constantin
Keyword(s):  
Molten Salts ◽  
Electrochemical Techniques ◽  
Active Species ◽  
Single Step ◽  
Cathodic Process ◽  
Molybdenum Electrode ◽  
Solute Interaction ◽  
Ohmic Drop ◽  
State Potential ◽  
Direct Discharge

The cathodic behavior of Ce3+ ions in LiF-NaF-BaF2, LiF-NaF-NaCl and NaCl-KCl molten salts at 730� C has been studied using different electrochemical techniques. The decomposition potential (Ed) and the cathodic overvoltage were determined by introducing NaCeF4 as electrochemical active species using steady-state potential-current curves recorded under galvanostatic conditions. The values of |Ed| were 1.85 V in LiF-NaF-BaF2, 2.114 V in LiF-NaF-NaCl and 2.538 V in NaCl-KCl, respectively. It was also found that the ohmic drop potential in melt is not dependent on NaCeF4 concentration and it rises as the current intensity increases. The Tafel slopes and other kinetic parameters were calculated on the assumption that the cathodic process consisted of direct discharge of Ce3+, with no solvent-solute interaction. In order to elucidate the mechanisn of cathodic process the cyclic voltammetry technique was finally used. From the evolution of the voltammograms we conclude that the electrochemical reduction of Ce3+ ion is actually a reversible process on the molybdenum electrode and cathodic reduction of Ce3+ takes place in one single step involving three electron exchange. Our study adds to the accumulating data and confirms available results of electrodeposition of metalic cerium from molten salts using NaCeF4 as solute.

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