The Vibrational Spectrum and Urey-Bradley Force Constants of the Trifluoromethyltrifluoroborate(1-) Anion
Keyword(s):
Infrared and Raman spectra for (K+) (CF3BF3−) have been obtained from 4000 to 50 cm−1. Spectral assignments were made on the basis of C3v symmetry using both 10B and 11B compounds. In addition, a normal coordinate analysis was performed to obtain the potential energy distribution of the normal modes. A Urey-Bradley type force field was used, and force constants obtained for the CF3 and BF3 groupings were compared to those in C2F6 and BF4−.
1988 ◽
Vol 43
(5)
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pp. 494-496
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1989 ◽
Vol 45
(8)
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pp. 835-843
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1981 ◽
Vol 36
(7)
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pp. 774-777
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1986 ◽
Vol 41
(10)
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pp. 1233-1237
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1955 ◽
Vol 76
(10)
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pp. 1132-1135
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1978 ◽
Vol 33
(6)
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pp. 709-713
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