1. Introduction: hydrogen storage as solution for a changing energy landscape

2018 ◽  
pp. 1-34
Author(s):  
Thomas Zell ◽  
Robert Langer
2011 ◽  
Vol 40 (15) ◽  
pp. 3796-3798 ◽  
Author(s):  
Igor A. Baburin ◽  
Bassem Assfour ◽  
Gotthard Seifert ◽  
Stefano Leoni

2018 ◽  
Vol 4 (1) ◽  
Author(s):  
Thomas Zell ◽  
Robert Langer

Abstract The expansion of sustainable technologies and infrastructures for the production and delivery of energy to the final consumer and the development of new technologies for energy production, storage and distribution, are challenging and inevitable tasks. Power plants based on the combustion of fossil fuel resources or nuclear power plants are not suitable to provide energy in the future due to significant disadvantages and dangers associated with these outdated technologies. The development of new sustainable technologies for the production of energy is desirable. Besides focusing on the production step, the change in global energy landscape requires also new and improved energy storage systems. Requirements for these storage solutions will strongly depend on the application. Storing energy by producing and consuming hydrogen is in this context a very attractive approach. It may be suitable for storage of energy for transportation and also for the bulk energy storage. Due to physical restrictions of high pressure hydrogen storage, alternative techniques are developed. This is, in turn, an ongoing task with multidisciplinary aspects, which combines chemistry, physics, material science and engineering. Herein, we review the production and consumption of energy, different energy storage applications, and we introduce the concept of hydrogen storage based on hydrogenation and dehydrogenation reactions of small molecules.


2018 ◽  
Vol 3 (12) ◽  
Author(s):  
Thomas Zell ◽  
Robert Langer

Abstract Changing demands on the energy landscape are causing the need for sustainable approaches. The shift toward alternative, renewable energy sources is closely associated with new demands for energy storage and transportation. Besides storage of electrical energy, also storage of energy by generating and consuming hydrogen (H2) is possible and highly attractive. Notably, both secondary energy vectors, electric energy and hydrogen, have practical advantages so that one should not ask “which one is better?” but “which one fits better the specific application?” Molecular hydrogen can be stored reversibly in form of formic acid (FA, HCOOH). In the presence of suitable catalysts, FA can be selectively decomposed to hydrogen and carbon dioxide (CO2). A CO2-neutral hydrogen storage cycle can be achieved when carbon dioxide serves as starting material for the production of the FA. Examples of CO2 hydrogenation to FA are known in the literature. Herein, the formal reverse reaction, the decomposition of FA to H2 and CO2 by different catalyst systems is reviewed and selected examples for reversible storage applications based on FA as hydrogen storage compound are discussed.


1997 ◽  
Vol 7 (3) ◽  
pp. 395-421 ◽  
Author(s):  
Jin Wang ◽  
Steven S. Plotkin ◽  
Peter G. Wolynes
Keyword(s):  

2015 ◽  
Vol 53 (12) ◽  
pp. 904-910 ◽  
Author(s):  
Myoung Youp Song ◽  
Daniel R. Mumm ◽  
Young Jun Kwak ◽  
Hye Ryoung Park
Keyword(s):  

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