Studies of Fluxionality in Pentachlorocyclopentadienylmercurials RHgC5Cl5 by Solution and Solid State 13C NMR and by 35Cl NQR Spectroscopy
Solution and magic-angle-spinning solid-state 13C NMR spectra are reported for η1-(pentachlorocyclopentadienyl)( pentamethylphenyl) mercury, C6Me5HgC5Cl5 (II). The latter suggests that II is fluxional in the solid state. Some expected consequences of fluxional behavior also appear in the 35Cl NQR spectra of II and several related pentachlorocyclopentadienylmercurials.
2000 ◽
Vol 1464
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pp. 165-175
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1985 ◽
Vol 107
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pp. 4898-4904
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2014 ◽
Vol 92
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pp. 9-15
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1993 ◽
Vol 1
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pp. 345-353
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2013 ◽
Vol 138
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pp. 184201
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