We Are Never Ever Getting (back to) Ideal Symmetry: Structure and Luminescence in a Ten-Coordinated Europium(III) Sulfate Crystal

Our theoretical treatment of electronic structure in coordination complexes often rests on assumptions of symmetry. Experiments rarely provide fully symmetric systems to study. In solution, fluctuation in solvation, variations in conformation, and even changes in constitution occur and complicates the picture. In crystals, lattice distortion, energy transfer, and phonon quenching is in play, but we are able to have distinct symmetries. Yet the question remains: How is the real symmetry in a crystal compared to ideal symmetries? Moreover, at what level of detail do we need to study a system to determine, if the electronic structure behaves as if it has ideal symmetry? Here, we have revisited the Continues Shape Measurement (CShM) approach developed by Ruiz-Martínez and Alvarez to evaluate the structure of ten-coordinated europium(III) ions in a K5Na[Eu2(SO4)6] structure. By comparing the result of the symmetry deviation analysis to luminescence data, we are able to show the effect of small deviations from ideal symmetry. We suggest using a symmetry deviation value, σideal, determined by using our updated approach to Continues Shape Measurements, where we also align the structure via our AlignIt code. AlignIt includes normalization and relative orientation in the symmetry comparison, and by combining the calculated values with the experimentally determined energy level splitting, we were able create the first point on a scale that can show how close to ideal an experimental structure actually is.

Synthesis, Spectral Study and Theoretical Treatment of 2-(2-(4-bromocyclohexa-1, 3-dienyl)-4-oxo-2H- benz [1, 3] oxazin-3(4H)-ylamino)-2-oxoethyl carbamimidothioate and Derivatives.

The standard heat of formation (ΔHof) and binding energy (ΔEb) for the free compound and their derivatives are calculated by using the PM3 method at 273K of Hyperchem.-8.07 program. The compound is more stable than their derivatives. furthermore to investigate the reactive site of the molecules the electrostatic potential of free derivatives is measured and pm3 is used to evaluate the vibrational spectra of the free derivatives, the frequencies are obtained approximately agreed with those values experimentally found; in addition, the calculation helps to assign clearly the most diagnostic bands .

Thermal Response and Thermochromism of Methyl Red-Based Copolymer Systems - Coupled Responsiveness in Critical Solution Behaviour and Optical Absorption Properties

Until now, only limited experimental knowledge and sparse theoretical treatment about the mechanisms of thermochromism of azo dyes in solution has been available. Especially the coupling of thermoresponsiveness of polymers...

Maximum ground level concentration Of air pollutant

The emission of an air pollutant from an elevated point source according to Gaussian plume model has been presented. Au. elementary theoretical treatment for both the highest possible ground-level concentration and the downwind distance at which this maximum occurs for different stability classes has been constructed. The effective height release modification was taken into consideration. An illustrative case study, namely, the emission from the research reactor in Inchas, has been studied. The results of these analytical treatments and of the derived semi-empirical formulae are discussed and presented in few illustrative diagrams.

Effects of Timing Noise on Square-Wave Optoelectronic Oscillators

Optoelectronic oscillators produce microwave-modulated optical beams without external modulation. The most commonly studied types produces narrow-band output, i.e., optical output modulated by a sinusoid, in which case phase noise determines key figures of merit that limit device performance. Nonetheless, other types of modulated signals have been exhibited by optoelectronic oscillators, including square waves. In this work we provide a theoretical treatment of the power spectral density of a microwave self-modulated optical periodic, but non-sinusoidal, oscillator in the presence of timing noise (as phase noise is only defined for a single sinusoid) and focus on the case of square waves. We consider the effects of timing noise on the power spectral density and autocorrelation function of the modulation signal.

A Model of Spectral Line Broadening in Signal Forecasts for Line-intensity Mapping Experiments

Line-intensity mapping observations will find fluctuations of integrated line emission are attenuated by varying degrees at small scales due to the width of the line emission profiles. This attenuation may significantly impact estimates of astrophysical or cosmological quantities derived from measurements. We consider a theoretical treatment of the effect of line broadening on both the clustering and shot-noise components of the power spectrum of a generic line-intensity power spectrum using a halo model. We then consider possible simplifications to allow easier application in analysis, particularly in the context of inferences that require numerous, repeated, fast computations of model line-intensity signals across a large parameter space. For the CO Mapping Array Project and the CO(1–0) line-intensity field at z ∼ 3 serving as our primary case study, we expect a ∼10% attenuation of the spherically averaged power spectrum on average at relevant scales of k ≈ 0.2–0.3 Mpc−1 compared to ∼25% for the interferometric Millimetre-wave Intensity Mapping Experiment targeting shot noise from CO lines at z ∼ 1–5 at scales of k ≳ 1 Mpc−1. We also consider the nature and amplitude of errors introduced by simplified treatments of line broadening and find that while an approximation using a single effective velocity scale is sufficient for spherically averaged power spectra, a more careful treatment is necessary when considering other statistics such as higher multipoles of the anisotropic power spectrum or the voxel intensity distribution.

The Dilemma of Knowledge Transfer in Early Independent Indonesia

This article addresses the dilemma of knowledge transfer at the time of decolonization and early independence in Indonesian history. There was an urgently felt need to replace Dutch knowledge as far as possible with knowledge held by Indonesians or imported from foreign countries other than the Netherlands. Concurrently, from the time of Indonesia’s independence there was also a necessity to retain or gain access to practical knowledge required for economic development The article argues that this dilemma was resolved by a mix of policies geared towards different levels of sophistication of the knowledge involved. The article contains a brief theoretical treatment of this dilemma, followed by a global overview of policies implemented. A separate case study on the key banking sector serves to demonstrate the possibilities and constraints in effectuating a transfer of knowledge soon after independence.