Reaktionen von α-Ketoaziden mit N,N-Dimethylammo-nitrosobenzol Darstellung von α-Imino-β-ketonitrilen und deren Redoxeigenschaften / Reactions of α-Ketoazides with N,N-Dimethylamino-nitrosobenzol Synthesis of α-Imino-β-Ketonitriles and their Redox Properties

1983 ◽  
Vol 38 (8) ◽  
pp. 930-933 ◽  
Author(s):  
Dierk Knittel
Keyword(s):  
Electrochemical Properties ◽  
Redox Properties ◽  
Nitroso Compounds ◽  
Aromatic Nitroso Compounds

A survey about the reaction between α-azidoacetophenones with aromatic nitroso compounds is given. The synthesis of α-imino-β-ketonitriles and some electrochemical properties of this class are described.

Influence of Metal Core Composition on Redox Properties and Photoreactivity of the Clusters [H4-xRu4-xRhx(CO)12] (x = 0, 2, 3, 4)

2001 ◽  
Vol 66 (7) ◽  
pp. 1062-1077 ◽  
Author(s):  
Maarten J. Bakker ◽  
Tapani A. Pakkanen ◽  
František Hartl
Keyword(s):  
Electrochemical Properties ◽  
Electrochemical Reduction ◽  
Redox Properties ◽  
Metal Core ◽  
Loss Product ◽  
Condensation Reactions ◽  
Core Composition ◽  
Co Dissociation ◽  
Major Reduction

Electrochemical properties of tetrahedral clusters [H2Ru2Rh2(CO)12], [HRuRh3(CO)12] and [Rh4(CO)12] were investigated in order to evaluate the influence of metal core composition in the series [H4-xRu4-xRhx(CO)12] (x = 0-4). The cluster [H3Ru3Rh(CO)12] was not available in sufficient quantities. As reported for [H4Ru4(CO)12], electrochemical reduction of the hydride-containing clusters [H2Ru2Rh2(CO)12] and [HRuRh3(CO)12] also results in (stepwise) loss of hydrogen, producing the anions [HRu2Rh2(CO)12]-, [Ru2Rh2(CO)12]2- and [RuRh3(CO)12]-. These anions can also be prepared from the neutral parent clusters via chemical routes. Electrochemical reduction of [Rh4(CO)12] does not result in the formation of any stable tetranuclear anion. Instead, [Rh5(CO)15]- and [Rh6(CO)15]2- are the major reduction products detected in the course of IR spectroelectrochemical experiments. Most likely, these cluster species are formed from the secondary CO-loss product [Rh4(CO)11]2- by fast redox condensation reactions. Their reoxidation regenerates parent [Rh4(CO)12], together with some [Rh6(CO)16]. Unlike [H4Ru4(CO)12] that undergoes photochemical CO-dissociation, [H2Ru2Rh2(CO)12] and [Rh4(CO)12] are completely photostable in neat hexane and dichloromethane as well as in the presence of oct-1-ene.

Synthesis, Characterization, Investigation of Capacitance and Redox Properties of Self-assembled Phe-Phe with Ferrocene Conjugates

2021 ◽  
Author(s):  
Om Shanker Tiwari
Keyword(s):  
Nucleic Acid ◽  
Electrochemical Properties ◽  
Self Assembly ◽  
Peptide Nucleic Acid ◽  
Redox Properties ◽  
Self Assembled ◽  
Acid Unit

The synthesis, nanostructure self-assembly and electrochemical properties of a series of ferrocene conjugated peptides derived from the dipeptide Phe-Phe, nucleoside and the peptide nucleic acid unit which are covalently attached...

scholarly journals Radical Polymerization of Styrene in the Presence of Aromatic Nitroso Compounds

1970 ◽  
Vol 27 (300) ◽  
pp. 269-275
Author(s):  
Akio Yoneda ◽  
Makoto Tanaka ◽  
Niro Murata
Keyword(s):  
Radical Polymerization ◽  
Nitroso Compounds ◽  
Aromatic Nitroso Compounds

scholarly journals Discharge Characteristics of Aromatic Nitroso Compounds-Carbon Composite Electrodes for Lithium Primary Cells

1993 ◽  
Vol 61 (7) ◽  
pp. 724-726
Author(s):  
Naoaki KUMAGAI ◽  
Hironobu FUKAHORI ◽  
Nobuko KUMAGAI ◽  
Kazuo TANNO
Keyword(s):  
Carbon Composite ◽  
Nitroso Compounds ◽  
Composite Electrodes ◽  
Primary Cells ◽  
Discharge Characteristics ◽  
Aromatic Nitroso Compounds

scholarly journals Compounds Related to Acridine. I. Condensation of Acridine Derivatives Having Active Methyl Group and Aromatic Nitroso Compounds

1963 ◽  
Vol 36 (11) ◽  
pp. 1477-1485 ◽  
Author(s):  
Otohiko Tsuge ◽  
Minoru Nishinohara ◽  
Masashi Tashiro
Keyword(s):  
Nitroso Compounds ◽  
Methyl Group ◽  
Acridine Derivatives ◽  
Active Methyl ◽  
Aromatic Nitroso Compounds

Aromatic nitroso compounds as .pi. acids in the zerovalent nickel triad metal complexes and the metal-assisted atom-transfer reactions with donor reagents

1976 ◽  
Vol 15 (3) ◽  
pp. 656-660 ◽  
Author(s):  
Sei. Otsuka ◽  
Yoshimasa. Aotani ◽  
Yoshitaka. Tatsuno ◽  
Toshikatsu. Yoshida
Keyword(s):  
Metal Complexes ◽  
Transfer Reactions ◽  
Nitroso Compounds ◽  
Atom Transfer ◽  
Atom Transfer Reactions ◽  
Aromatic Nitroso Compounds

ChemInform Abstract: THE REACTION OF AROMATIC NITROSO COMPOUNDS WITH CYANIDE ION IN APROTIC SOLVENTS

1975 ◽  
Vol 6 (47) ◽  
pp. no-no
Author(s):  
J. C. TRISLER ◽  
P. H. DELAND ◽  
M. M. GOODGAME
Keyword(s):  
Nitroso Compounds ◽  
Aprotic Solvents ◽  
Cyanide Ion ◽  
Aromatic Nitroso Compounds

14N Study of Aromatic Nitroso Compounds

HFI/NQI 2004 ◽  
2008 ◽  
pp. 579-583
Author(s):  
N. Beepath ◽  
D. Stephenson
Keyword(s):  
Nitroso Compounds ◽  
Aromatic Nitroso Compounds
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