Übergangsmetallkomplexe mit Schwefelliganden, CI*. Synthese und Struktur von N2H5[Fe(N2H4)(S2C6H4)2] · 1,33N2H4 / Transition Metal Complexes with Sulfur Ligands, Cl*. Synthesis and Structure of N2H5[Fe(N2H4)(S2C6H4)2] · 1,33N2H4
1994 ◽
Vol 49
(5)
◽
pp. 660-664
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Keyword(s):
X Ray
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Attempts to coordinate N2H4 to [Fe(S2C6H4)2] fragments lead to N2H5[Fe(N2H4)(S2C6H4)2], which crystallizes from MeOH/N2H4 solutions as the solvate [(N2H5){Fe(N2H4)(S2C6H4)2} · 1,33 N2H4]. 1, and has been characterized by X-ray structure analysis. 1 contains three discrete N2H5+ cations, four N2H4 solvate molecules and three independent [Fe(N2H4)(S2C6H4)2]- anions which are connected via an extended network of N-H ··· N and N-H ··· S bridges. N2H5[Fe(N2H4)(S2ChH4)2] and 1 contain high-spin Fe(III) centers and labile N2H4 ligands.
1991 ◽
Vol 46
(12)
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pp. 1601-1608
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1998 ◽
Vol 53
(2)
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pp. 153-156
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Keyword(s):
1990 ◽
Vol 175
(2)
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pp. 231-239
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Keyword(s):
1986 ◽
Vol 41
(10)
◽
pp. 1230-1238
◽
1991 ◽
Vol 46
(11)
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pp. 1449-1458
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