A mixed-ligand dihydrobis(2-mercapto-4-methylthiazolyl)borate) bismuth complex: [Bi(btMe)(phen)Cl2]

2015 ◽  
Vol 70 (3) ◽  
pp. 203-206 ◽  
Author(s):  
Muhammad Imran ◽  
Beate Neumann ◽  
Norbert W. Mitzel

Abstract[Bi(btMe)(phen)Cl2] (btMe = dihydrobis(2-mercapto-4-methylthiazolyl)borate), a mixed-ligand bismuth complex, was prepared from BiCl3, phenanthroline and Na(btMe) and characterized by nuclear magnetic resonance spectroscopy as well as single-crystal X-ray diffraction. It possesses a BiS2N2Cl2 core with distorted octahedral environment constituted by two sulfur atoms of the dipodal boron-centered soft ligand (btMe)–, two nitrogen atoms of the phenanthroline ligand and two chloro ligands.

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