Test Method for Assignment of the Glass Transition Temperatures by Differential Scanning Calorimetry

2003 ◽  
Author(s):  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Glass Transition ◽  
Test Method ◽  
Transition Temperatures ◽  
Scanning Calorimetry ◽  
Glass Transition Temperatures

Synthesis and Properties of Poly (N-arylenebenzimidazole ketone)s

2014 ◽  
Vol 881-883 ◽  
pp. 165-168
Author(s):  
Xiang Wang Cui ◽  
Lin Zhang
Keyword(s):  
Differential Scanning Calorimetry ◽  
Glass Transition ◽  
Coupling Reaction ◽  
Transition Temperatures ◽  
Scanning Calorimetry ◽  
Glass Transition Temperatures

Two bis (benzimidazoyl) monomers were synthesized, and Poly (N-arylenebenzimidazole ketone) s were prepared by N-C coupling reaction that replaced the NH sites from the bis (benzimidazolyl) derivatives with activated difluorides monomers in sulfolane at 210 °C. All the resulting polymers showed easy solubility compared with traditional polybenzimidazoles. Differential scanning calorimetry and thermogravimetric measurements showed that the polymers had high glass transition temperatures (>240 °C), good thermostability and high decomposition temperatures (>460 °C).

Glass Transition Behavior of Polyisoprene: The Influence of Molecular Weight, Terminal Hydroxy Groups, Microstructure, and Chain Branching

1982 ◽  
Vol 55 (1) ◽  
pp. 245-252 ◽  
Author(s):  
C. Kow ◽  
M. Morton ◽  
L. J. Fetters ◽  
N. Hadjichristidis
Keyword(s):  
Molecular Weight ◽  
Differential Scanning Calorimetry ◽  
Glass Transition ◽  
Low Molecular Weight ◽  
Hydroxyl Groups ◽  
Transition Temperatures ◽  
Scanning Calorimetry ◽  
Chain Branching ◽  
Glass Transition Temperatures ◽  
Hydroxy Groups

Abstract The glass transition temperatures for a series of high-1,4 linear and star-branched polyisoprenes have been measured by differential scanning calorimetry. The Fox-Flory relation for the linear polyisoprenes was found to be Tg=Tg∞−1.76×104Mn−1. The influence of hydroxyl groups on Tg was also examined for low molecular weight (<2.2×104) polyisoprenes.

Sign in / Sign up

Export Citation Format

Share Document