Synthesis and X-ray structure of hexakis (N,N-dimethylacetamide-O)magnesium tetrachloromagnesate

Author(s):  
L. Pavanello ◽  
P. Visonà ◽  
S. Bresadola ◽  
G. Bandoli

AbstractThe preparation and the X-ray single-crystal structure determination of {Mg[CHThe obtained compound shows an ionic structure in which the Mg cation is coordinated by six dimethylaccetamide moieties through the oxygen atoms and the tetrahedral [MgCl

1993 ◽  
Vol 46 (11) ◽  
pp. 1811 ◽  
Author(s):  
CJ Adams ◽  
MI Bruce ◽  
BW Skelton ◽  
AH White

The synthesis and room-temperature single-crystal X-ray structure determination of the title compound are recorded. Crystals are monoclinic, P 21/c, a 14.43(2), b 18.39(1), c 23.64(3) Ǻ, β 123.16(7)°, Z = 4, isostructural with the recently described Fe3Ru5 analogue; R was 0.048 for 6892 'observed' data [I > 3σ(I)]. The cluster is one of the few containing separated carbide ligands within a polyhedral metal skeleton, consisting of an Ru5C square pyramid and an Ru6C octahedron sharing a triangular face, with two PPh2 groups bridging opposite Ru-Ru vectors in each polyhedron.


Author(s):  
H. D. Lutz ◽  
H. Möller ◽  
M. Maneva ◽  
W. Paulus ◽  
A. Cousson ◽  
...  

AbstractThe crystal structure of Be(IO


Author(s):  
Vito Di Noto ◽  
Silvano Bresadola ◽  
Roberto Zannetti ◽  
Maria Viviani ◽  
Giuliano Bandoli

AbstractThe preparation and the X-ray single crystal structure determination of [Mg(CThe [Mg(C


Author(s):  
P. Ballirano ◽  
R. Caminiti ◽  
C. Sadun ◽  
V. M. Coiro ◽  
G. Mancini ◽  
...  

AbstractThe structures of cetylpyridiniumammonium bromide (CPyB) and cetylquinuclidinium bromide (CQB), two tetraalkylammonium bromide surfactants, are reported. In particular, whereas the structure solution of CPyB was carried out through conventional single-crystal diffractometry, the structure of CQB has been determined by means of powder diffractometry. CPyB crystallizes in


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