Synthesis and Single Crystal Structure Determination of Bis(carbido)bis(μ-diphenylphosphido)heptadecacarbonyloctaruthenium-Dichloromethane (1/1), Ru8(μ6-C)(μ5-C)(μ-PPh2)2(CO)17.CH2Cl2
Keyword(s):
The synthesis and room-temperature single-crystal X-ray structure determination of the title compound are recorded. Crystals are monoclinic, P 21/c, a 14.43(2), b 18.39(1), c 23.64(3) Ǻ, β 123.16(7)°, Z = 4, isostructural with the recently described Fe3Ru5 analogue; R was 0.048 for 6892 'observed' data [I > 3σ(I)]. The cluster is one of the few containing separated carbide ligands within a polyhedral metal skeleton, consisting of an Ru5C square pyramid and an Ru6C octahedron sharing a triangular face, with two PPh2 groups bridging opposite Ru-Ru vectors in each polyhedron.
1992 ◽
Vol 100
(2)
◽
pp. 341-355
◽
2017 ◽
Vol 81
(5)
◽
pp. 1063-1071
◽
1994 ◽
Vol 209
(12)
◽
1996 ◽
Vol 211
(3)
◽
1991 ◽
Vol 3
(42)
◽
pp. 8173-8180
◽
1993 ◽
Vol 204
(2)
◽
1991 ◽
Vol 168
(2)
◽
pp. 377-382
◽