CRYSTAL STRUCTURE OF A NEW BINUCLEAR COMPLEX bis(2,4,6,8-TETRAMETHYL-2,4,6,8-TETRAAZABICYCLO(3.3.0)OCTANE-3,7-DIONE-O,O)-TETRAAQUA-hexakis(NITRATO-O,O)-DIEUROPIUM(III)

2016 ◽  
Keyword(s):  
Crystal Structure ◽  
Binuclear Complex

A cyano bridged copper(ii)-iron(iii) binuclear complex, (cutren)fe(cn)5no 2h2o crystal structure and magnetic properties

1998 ◽  
Vol 43 (4) ◽  
pp. 273-280 ◽  
Author(s):  
Jianz Hong Zou ◽  
Xing You Xu ◽  
Zheng Xu ◽  
Xiao Zeng You ◽  
Xiao Ying Huang ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Binuclear Complex

Synthesis of an Unprecedented H-stitched Binuclear Crystal Structure Based on Selective Fluorescence Recognition of Zn2+ in Newly Synthesized Schiff Base Ligand with DFT and Imaging Application in Living Cells

2021 ◽  
Author(s):  
SOUMYA SUNDAR MATI ◽  
Dr. SAUGATA KONAR ◽  
BOBY SAMAI
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Elemental Analysis ◽  
Schiff Base Ligand ◽  
Binuclear Complex ◽  
Living Cells ◽  
X Ray Diffraction ◽  
Schiff Base Ligands ◽  
X Ray ◽  
Imaging Application

A zinc coordinated rare binuclear complex was synthesised and characterized by elemental analysis and single-crystal X-ray diffraction. Two mononuclear units formed by two Schiff base ligands 2-((2-(pyrimidin-2-yl)hydrazono)methyl)phenol (PHP) coordinated with...

Synthesis, Crystal Structure and Properties of the Binuclear Complex [Sm2(C10H9N2O4)2(C10H8N2O4)2(H2O)4]

2008 ◽  
Vol 38 (10) ◽  
pp. 755-760 ◽  
Author(s):  
Feng Liu ◽  
Weiping Zhang ◽  
Shuiyang He ◽  
Liujie Wang ◽  
Xiangrong Liu
Keyword(s):  
Crystal Structure ◽  
Binuclear Complex ◽  
Structure And Properties

scholarly journals Bis{μ-2,2′-[(3,4-dithiahexane-1,6-diyl)bis(nitrilomethanylylidene)]bis(4-bromophenolato)-κ4O,N,N′,O′}dicopper(II)

2018 ◽  
Vol 74 (1) ◽  
pp. 38-40
Author(s):  
Julia A. Rusanova ◽  
Dmytro Bederak ◽  
Vladimir N. Kokozay
Keyword(s):  
Crystal Structure ◽  
Title Compound ◽  
Binuclear Complex ◽  
Coordination Geometry ◽  
Two Dimensional ◽  
Chelating Ligand ◽  
Dimensional Network ◽  
Coordination Bonds

The crystal structure of the title compound, [Cu2(C18H12Br2N4O2S2)2], consists of binuclear complex units which lie across inversion centres and are connected by weak Cu—O coordination bonds forming chains along thebaxis. The CuIIion is five-coordinated by two N atoms and two O atoms of the chelating ligand and one symmetry-related O atom forming a square-pyramidal coordination geometry. In the crystal, short S...Br contacts connect neighbouring chains into a two-dimensional network parallel to (101).

Synthesis, crystal structure and photoluminescence of Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6

2018 ◽  
Vol 73 (5) ◽  
pp. 319-322
Author(s):  
Arnd Vogler ◽  
Michael Bodensteiner
Keyword(s):  
Crystal Structure ◽  
Excited State ◽  
Binuclear Complex ◽  
Mlct State ◽  
Fluorescence And Phosphorescence

AbstractThe binuclear complex Re(I)2(μ-4,4′-bipyridine)(8-quinolinolato)2(CO)6 has been prepared and characterized including the crystal structure. This complex shows, dependent on the conditions, three emissions, which originate from the quinolinolate IL excited state (fluorescence and phosphorescence) and from a Re(I) to 4,4′-bipyridine MLCT state (phosphorescence).

Synthesis and crystal structure of the binuclear complex Cs3[Mo 2 V O2(μ-S)2Cl4(H2O)2]Cl

2014 ◽  
Vol 40 (4) ◽  
pp. 195-199 ◽  
Author(s):  
P. L. Sinkevich ◽  
V. S. Korenev ◽  
P. A. Abramov ◽  
A. V. Rogachev ◽  
Yu. A. Laricheva ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Binuclear Complex ◽  
Synthesis And Crystal Structure

scholarly journals Crystal structure of μ-oxalodihydroxamato-bis[(2,2′-bipyridyl)(dimethyl sulfoxide-κO)copper(II)] bis(perchlorate)

2016 ◽  
Vol 72 (2) ◽  
pp. 147-150
Author(s):  
Irina A. Odarich ◽  
Anna V. Pavlishchuk ◽  
Valentina A. Kalibabchuk ◽  
Matti Haukka
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Dimethyl Sulfoxide ◽  
Binuclear Complex ◽  
Axis Direction ◽  
Electrical Neutrality

The centrosymmetric binuclear complex, [Cu2(C2H2N2O4)(C10H8N2)2(C2H6OS)2](ClO4)2, contains two copper(II) ions, connected through an N-deprotonated oxalodihydroxamic acid dianion, two terminal 2,2′-bipyridine ligands, and two apically coordinating dimethylsulfoxide molecules. Two non-coordinating perchlorate anions assure electrical neutrality. The copper(II) ions in the complex dication [Cu2(C10H8N2)2(μ-C2H2N2O4)(C2H6SO)2]2+are in an O2N3square-pyramidal donor environment, the Cu–Cu separation being 5.2949 (4) Å. Two hydroxamate groups in the deprotonated oxalodihydroxamic acid are locatedtransto one each other. In the crystal, O—H...O and C—H...O hydrogen bonds link the complex cations to the perchlorate anions. Further C—H...O hydrogen bonds combine with π–π contacts with a centroid-to-centroid separation of 3.6371 (12) Å to stack the molecules along thea-axis direction.

Synthesis, crystal structure, magnetic properties, and thermodynamic and electrochemical studies of the binuclear complex [(.mu.-oxalato)bis[(1,4,8,11-tetraazacyclotetradecane)nickel(II)] nitrate

1988 ◽  
Vol 27 (23) ◽  
pp. 4174-4179 ◽  
Author(s):  
Luigi P. Battaglia ◽  
Antonio Bianchi ◽  
Anna Bonamartini Corradi ◽  
Enrique Garcia-Espana ◽  
Mauro Micheloni ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Binuclear Complex ◽  
Electrochemical Studies

ChemInform Abstract: Synthesis, Crystal Structure, Magnetic Properties, and Thermodynamic and Electrochemical Studies of the Binuclear Complex (μ-Oxalato)bis((1,4,8,11-tetraazacyclotetradecane)nickel(II)) Nitrate.

ChemInform ◽  
1989 ◽  
Vol 20 (11) ◽  
Author(s):  
L. P. BATTAGLIA ◽  
A. BIANCHI ◽  
A. BONAMARTINI CORRADI ◽  
E. GARCIA-ESPANA ◽  
M. MICHELONI ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Binuclear Complex ◽  
Electrochemical Studies

scholarly journals Crystal structure of di-μ-hydroxido-bis[aqua(1,10-phenanthroline-κ2N,N′)copper(II)] naphthalene-2,6-dicarboxylate hexahydrate

2015 ◽  
Vol 71 (4) ◽  
pp. 360-362 ◽  
Author(s):  
Daniela Arias-Zárate ◽  
María Fernanda Ballesteros-Rivas ◽  
Rubén A. Toscano ◽  
Jesús Valdés-Martínez
Keyword(s):  
Crystal Structure ◽  
Binuclear Complex ◽  
Complex Cation ◽  
Three Dimensional ◽  
Water Molecules ◽  
Coordination Geometry ◽  
Supramolecular Architecture ◽  
Aromatic Rings ◽  
Phen Molecule ◽  
Lattice Water

In the title compound, [Cu2(OH)2(C12H8N2)2(H2O)2](C12H6O4)·6H2O, the two hydroxide groups bridge the two CuIIcations, forming a centrosymmetric binuclear complex cation, in which the CuIIcation is coordinated by a 1,10-phenanthroline (phen) molecule, one water molecule and two bridging hydroxide O atoms in a distorted N2O3square-pyramidal coordination geometry. The naphthalene-2,6-dicarboxylate anion is also located on an inversion centre. In the crystal, O—H...O hydrogen bonds link the cations, anions and lattice water molecules into a three-dimensional supramolecular architecture. Extensive π–π stacking is observed between the parallel or nearly parallel aromatic rings of adjacent phen ligands and naphthalenedicarboxylate anions, the centroid-to-centroid distances ranging from 3.4990 (16) to 3.8895 (16) Å.

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