In-Situ Raman Spectroscopy Studies of Room-Temperature and Hydrothermal Reactions
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ABSTRACTBy contracting with the Parr Instrument Company and Bruker Optical Systems, we have developed a system for continuous monitoring of hydrothermal and room temperature reactions by Raman spectroscopy. Using the uranyl peroxide cage cluster {[UO2(O2)(OH)]16[UO2(OM)2]4}24- (denoted {U20R}) and a coordination polymer made from uranyl ions and 4,4’-biphenyldicarboxylate as model systems, we demonstrate the spectroscopically observable changes associated with reaction progress and crystallization.
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1997 ◽
Vol 120
(1-2)
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pp. 99-105
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1997 ◽
Vol 430
(1-2)
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pp. 47-56
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2016 ◽
Vol 55
(5)
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pp. 2612-2619
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2022 ◽
pp. 100589
1985 ◽
Vol 29
(2)
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pp. 231-258
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