Fracture behavior of heat treated liquid crystalline polymers
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ABSTRACTThermotropic polymers are thermally treated in air at temperatures Ta, where ΔT =Ta- Ts→n=40°C, and Ts→n is the solid-to-nematic transition. Samples are extruded thin films of a series of thermotropic random copolyesters termed B-N, COTBP and RD1000. The thermal treatment produces a second endotherm without changing Ts→n for B-N and RD1000. However, for COTBP Ts→n is significantly increased. Regardless of the complex thermal behavior exhibited by the thermotropes, the thermal treatment produces a significant increase in Young's modulus, more than 30% for B-N and over 100% for COTBP. The increase in mechanical modulus is correlated with a thermally-induced fiber-like morphology.
2005 ◽
Vol 17
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pp. 149-160
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1993 ◽
Vol 225
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pp. 259-268
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1995 ◽
Vol 6
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pp. 230-236
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1984 ◽
Vol 19
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pp. 2085-2097
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2003 ◽
Vol 27
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pp. 393-402
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2004 ◽
Vol 53
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pp. 33-43
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1999 ◽
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