Relation Between the Chemical Short-Range Order in Liquid and Amorphous Alloys

1981 ◽  
Vol 8 ◽  
Author(s):  
C.N.J. Wagneri ◽  
H. Ruppersberg

ABSTRACTRecent advances in both diffraction theory and experiment have led to the determination of the topological and chemical short-range order in liquid alloys and metallic glasses. In binary alloys, three partial interference functions (or partial structure factors) must be determined to evaluate the Warren chemical short-range order parameter α. Examples of recent attempts to determine α in binary liquid and glassy alloys are given. In most glasses, studied so far, evidence exists for the occurrence of unlike nearest neighbor ordering which must be present in the liquid state.


1992 ◽  
Vol 47 (7-8) ◽  
pp. 826-832 ◽  
Author(s):  
H. Uhlig ◽  
L. Rohr ◽  
H.-J. Güntherodt ◽  
P. Fischer ◽  
P. Lamparter ◽  
...  

Abstract Amorphous Ni50Ta50-samples with their high crystallization temperature of 985 K were investigated. To evaluate the three partial structure factors of amorphous Ni50Ta50 one X-ray diffraction experiment was performed with Ni50Ta50 and two neutron diffraction experiments with Co10Ni40Ta50 and with Ni50Ta50, respectively. The Bhatia-Thornton partial structure factor SCC(Q) indicates rather strong chemical short range order which also explains the premaximum observed in the Faber-Ziman partial SNiNi(Q)-function. The nearest neighbor distance is 2.82 Å for Ni-Ni, 2.91 Å for Ta-Ta, and is shortest for Ni-Ta, 2.44 Å. The coordination numbers are NNiNi = 4.9, NTaTa = 8.2, and NNiTa = 6.0. We report on the chemical short range order and the possible binding behavior in a-Ni50Ta50 and compare the present results with those reported in the literature on a-Ni40Ti60 as well as on a-Ni55Ta45



1985 ◽  
Vol 46 (C8) ◽  
pp. C8-87-C8-92 ◽  
Author(s):  
R. Bellissent ◽  
J. Bigot ◽  
Y. Calvayrac ◽  
S. Lefebvre ◽  
A. Quivy




2003 ◽  
Vol 805 ◽  
Author(s):  
Dirk Holland-Moritz ◽  
Thomas Schenk ◽  
Virginie Simonet ◽  
Robert Bellissent

ABSTRACTThe short-range order of stable and deeply undercooled liquids of Al13(Co,Fe)4 alloys forming polytetrahedral phases is investigated by combining the containerless processing technique of electromagnetic levitation with elastic neutron scattering. Partial structure factors were inferred from the diffraction data which allow an analysis of both, the topological and the chemical short-range order of these alloy melts as a function of the temperature.



1985 ◽  
Vol 54 (12) ◽  
pp. 1059-1063 ◽  
Author(s):  
A. Hernando ◽  
V. Madurga ◽  
J.M. Barandiarán ◽  
O.V. Nielsen


AIP Advances ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 095203 ◽  
Author(s):  
Richard A. Laroche ◽  
Sivaraman Guruswamy


2013 ◽  
Vol 91 ◽  
pp. 166-169
Author(s):  
S. Stichleutner ◽  
E. Kuzmann ◽  
G.B. Lak ◽  
M. El-Sharif ◽  
C.U. Chisholm ◽  
...  


1992 ◽  
Vol 45 (9) ◽  
pp. 4695-4699 ◽  
Author(s):  
S. H. Ge ◽  
M. X. Mao ◽  
G. L. Chen ◽  
Z. H. Chen ◽  
C. L. Zhang ◽  
...  


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