QUANTITATIVE MEASUREMENTS OF DIESEL FUEL SPRAY CHARACTERISTICS IN THE NEAR-NOZZLE REGION USING X-RAY ABSORPTION

We have investigated the local structure of BiS2-based layered materials by Bi L3-edge extended X-ray absorption fine structure (EXAFS) measurements performed on single crystal samples with polarization of the X-ray beam parallel to the BiS2 plane. The results confirm highly instable nature of BiS2 layer, characterized by ferroelectric like distortions. The distortion amplitude, determined by the separation between the two in-plane (Bi-S1) bonds, is found to be highest in LaO0.77F0.23BiS2 with ΔR∼0.26 Å and lowest in NdO0.71F0.29BiS2 with ΔR∼0.13 Å. Among the systems with intrinsic doping, CeOBiS2 shows smaller distortion (ΔR∼0.15 Å) than PrOBiS2 (ΔR∼0.18 Å) while the highest distortion appears for EuFBiS2 revealing ΔR∼0.22 Å. It appears that the distortion amplitude is controlled by the nature of the RE(O,F) spacer layer in the RE(O,F)BiS2 structure. The X-ray absorption near edge structure (XANES) spectra, probing the local geometry, shows a spectral weight transfer that evolves systematically with the distortion amplitude in the BiS2-layer. The results provide a quantitative measurements of the local distortions in the instable BiS2-layer with direct implication on the physical properties of these materials.

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Characteristics of Gas-Dissolved Diesel Fuel Spray. 2nd Report. Spray Characteristics of Liquefied CO2 Mixed Fuel.

TRANSACTIONS OF THE JAPAN SOCIETY OF MECHANICAL ENGINEERS Series B ◽

10.1299/kikaib.63.3179 ◽

1997 ◽

Vol 63 (613) ◽

pp. 3179-3186

Author(s):

Jiro SENDA ◽

Ichiro SHIBATA ◽

Hajime FUJIMOTO

Keyword(s):

Diesel Fuel ◽

Fuel Spray ◽

Spray Characteristics ◽

Mixed Fuel

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X-ray microanalysis of thin specimens in the transmission electron microscope at voltages up to 1000 Kv.

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100109847 ◽

1978 ◽

Vol 36 (1) ◽

pp. 540-541

Author(s):

G. Cliff ◽

M.J. Nasir ◽

G.W. Lorimer ◽

N. Ridley

Keyword(s):

Electron Microscope ◽

Transmission Electron Microscope ◽

Weight Fraction ◽

Present Series ◽

Constant Independent ◽

X Ray ◽

Transmission Electron ◽

Series Of Experiments ◽

Image Position ◽

X Ray Absorption

In a specimen which is transmission thin to 100 kV electrons - a sample in which X-ray absorption is so insignificant that it can be neglected and where fluorescence effects can generally be ignored (1,2) - a ratio of characteristic X-ray intensities, I1/I2 can be converted into a weight fraction ratio, C1/C2, using the equationwhere k12 is, at a given voltage, a constant independent of composition or thickness, k12 values can be determined experimentally from thin standards (3) or calculated (4,6). Both experimental and calculated k12 values have been obtained for K(11<Z>19),kα(Z>19) and some Lα radiation (3,6) at 100 kV. The object of the present series of experiments was to experimentally determine k12 values at voltages between 200 and 1000 kV and to compare these with calculated values.The experiments were carried out on an AEI-EM7 HVEM fitted with an energy dispersive X-ray detector.

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