scholarly journals Synthesis of 1,5-Functionalized 1,2,3-Triazoles Using Ionic Liquid/Iron(III) Chloride as Efficient and Reusable Homogeneous Catalyst

2018 ◽  
Author(s):  
Antonio De Nino ◽  
Pedro Merino ◽  
Vincenzo Algieri ◽  
Monica Nardi ◽  
Maria Luisa Di Gioia ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Iron ◽  
Catalytic System ◽  
Dipolar Cycloaddition ◽  
Homogeneous Catalyst ◽  
Mechanistic Studies ◽  
Elimination Process ◽  
Cheap Method

An efficient, eco-compatible and very cheap method for the construction of triazoles via eliminative azide–olefin cycloaddition (EAOC) reaction has been developed by a catalytic system IL/FeCl3, offering an highly regioselective approach to structurally diverse 1,5-disubstituted 1,2,3-triazoles in up to 95% yield. This strategy features the reuse of catalytic system through simple operations. Mechanistic studies indicated that an asynchronous concerted dipolar cycloaddition-elimination process might be involved.

Topochemical pyrolytic synthesis of quasi-Mxene hybrids via ionic liquid-iron phthalocyanine as a self-template

2019 ◽  
Vol 55 (6) ◽  
pp. 771-774
Author(s):  
Ruixuan Chen ◽  
Kun Rui ◽  
Xiaofei Yang ◽  
Aoming Huang ◽  
Yao Zhang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Liquid Iron ◽  
Iron Phthalocyanine

A novel quasi-Mxene structure hybrid is first realized through topochemical pyrolysis with the assistance of an ionic liquid.

Synthesis of Polyester Amide by Carbonylation–Polycondensation Reaction Using Immobilized Palladium Metal Containing Ionic Liquid on SBA-15 as a Phosphine-Free Catalytic System

2015 ◽  
Vol 145 (3) ◽  
pp. 824-833 ◽  
Author(s):  
Anilkumar Satapathy ◽  
Sandip T. Gadge ◽  
Etty N. Kusumawati ◽  
Kei Harada ◽  
Takehiko Sasaki ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Polycondensation Reaction ◽  
Palladium Metal

scholarly journals Asymmetric transfer hydrogenation of prochiral ketones catalyzed by aminosulfonamide-ruthenium complexes in ionic liquid

2011 ◽  
Vol 9 (1) ◽  
pp. 175-179 ◽  
Author(s):  
Zhongqiang Zhou ◽  
Yong Sun ◽  
Aiqing Zhang
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Ruthenium Complexes ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Prochiral Ketones

AbstractChiral aminosulfonamides containing imidazolium group were used as ligands for the ruthenium(II)-catalyzed asymmetric transfer hydrogenation of prochiral ketones in ionic liquid, affording good to excellent conversions and enantiomeric excesses. The catalytic system could be easily recovered and reused several times.

Silver-Catalyzed Decarboxylative Radical Relay Difluoroalkylation-Carbocyclization: Convenient Access to CF2-Containing Quinolinones

2021 ◽  
Author(s):  
Feng Zhao ◽  
Sa Guo ◽  
Yan Zhang ◽  
Ting Sun ◽  
Xin Wang ◽  
...  
Keyword(s):  
Catalytic System ◽  
Mechanistic Studies ◽  
Convenient Access

We report a practical Ag-catalyzed decarboxylative difluoroalkylation–carbocyclization reaction. Various structurally diverse gem-fluorinated quinolinones were obtained in moderate to good yields. Mechanistic studies suggested that the catalytic system involved a formal...

A one-pot synthesis of benzimidazoles via aerobic oxidative condensation of benzyl alcohols with o-phenylenediamines catalyzed by [MIMPs]+Cl-/NaNO2/TEMPO

2020 ◽  
Vol 44 (9-10) ◽  
pp. 557-565
Author(s):  
Zhenzhen Geng ◽  
Hong-yu Zhang ◽  
Guohui Yin ◽  
Yuecheng Zhang ◽  
Jiquan Zhao
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Sodium Nitrite ◽  
High Efficiency ◽  
Oxidative Condensation ◽  
Imidazolium Chloride ◽  
One Pot ◽  
Benzyl Alcohols ◽  
One Pot Synthesis ◽  
The One

The ionic liquid 1-methyl-3-(3-sulfopropyl)imidazolium chloride ([MIMPs]+Cl-) in combination with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and sodium nitrite (NaNO2) as a catalytic system demonstrates high efficiency in the one-pot two-step aerobic oxidative condensation of benzyl alcohols with 1,2-phenylenediamines to give benzimidazoles. Various benzimidazoles are obtained in good to excellent yields by this strategy.

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