scholarly journals Electrochemical oxidation of of Hydrolyzed Polyacrylamide (HPAM) at Ti/SnO2-Sb2O3/β-PbO2 Anode. Degradation Kinetics and Mechanisms

Author(s):  
Yanhe Han ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 103773 ◽  
Author(s):  
Lei Jiani ◽  
Xu Zhicheng ◽  
Xu Hao ◽  
Qiao Dan ◽  
Liao Zhengwei ◽  
...  

2013 ◽  
Vol 139 (6) ◽  
pp. 810-821 ◽  
Author(s):  
François Zaviska ◽  
Patrick Drogui ◽  
Jean-François Blais ◽  
Guy Mercier ◽  
Samuel De La Rochebrochard d’Auzay

2011 ◽  
Vol 233-235 ◽  
pp. 1674-1677
Author(s):  
Ting Yu

With mixed rare earth (La, Ce, Nd) doping Ti/TiO2 electrode for the anode, degradation situation of oilfield wastewater was studied. The results showed that electrocatalysis technology excels at treating oilfield wastewater. Electrocatalytic oxidation reaction kinetic equation: At=A0exp(-7.02×10-7D-1.42M-1.66U3.40t).


2019 ◽  
Vol 84 (2) ◽  
pp. 187-198 ◽  
Author(s):  
Olesia Shmychkova ◽  
Tatiana Luk’yanenko ◽  
Larisa Dmirtikova ◽  
Alexander Velichenko

An investigation is reported on lead dioxide electrodeposition from methanesulfonate electrolytes additionally containing Ni2+ ions. It is shown that lead dioxide electrodes micromodified by nickel have different physico-chemical properties vs. nonmodified PbO2-anodes that are formed during the deposition. Electrocatalytical reactivity of electrodes involved in comparison to both the oxygen evolution, as well as to the electrooxidation of 2,4- dichlorophenoxyacetic (2,4-D) acid is investigated. Processes of electrochemical oxidation of 2,4-D on various materials occur qualitatively with the same mechanism and differ only in the rate. It is shown that the Ni-PbO2-anode possesses the highest electrocatalytic activity: the destruction rate of 2,4-D on it increases in 1.5 times in comparison with nonmodified lead dioxide. The COD of a 0.4 mM solution of 2,4-D, determined by the dichromate method, is 90.0 mg dm-3 which is 94 % of the theoretical value.


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