Is Circularly Polarized Light an Effective Reagent For Asymmetric Synthesis?

Mini-Reviews in Organic Chemistry ◽

10.2174/1570193054368891 ◽

2005 ◽

Vol 2 (3) ◽

pp. 203-209 ◽

Author(s):

Richard Pagni ◽

Robert Compton

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized

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Absolute asymmetric synthesis. I. Mechanism of the photochemical synthesis of nonracemic helicenes with circularly polarized light. Wavelength dependence of the optical yield of octahelicene

Journal of the American Chemical Society ◽

10.1021/ja00757a029 ◽

1972 ◽

Vol 94 (2) ◽

pp. 494-498 ◽

Author(s):

William J. Bernstein ◽

Melvin Calvin ◽

Ole Buchardt

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Wavelength Dependence ◽

Photochemical Synthesis ◽

Optical Yield ◽

Light Wavelength ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Absolute Asymmetric Synthesis

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Synchronous enantiomeric enrichment of both reactant and product by absolute asymmetric synthesis using circularly polarized light. Part 1. Theoretical and experimental verification of the asymmetric photoisomerization of methyl norbornadiene-2-carboxylate to methyl quadricyclane-1-carboxylate†

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/b100751n ◽

2001 ◽

pp. 1693-1700 ◽

Author(s):

Hideo Nishino ◽

Asao Nakamura ◽

Yoshihisa Inoue

Keyword(s):

Asymmetric Synthesis ◽

Experimental Verification ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Enantiomeric Enrichment ◽

Absolute Asymmetric Synthesis ◽

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Synchronous enantiomeric enrichment of both reactant and product by absolute asymmetric synthesis using circularly polarized light. Part 2. Verification of the validity of assuming first-order kinetics upon deriving the equation for the relationship between conversion and enantiomeric excess

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/b100749l ◽

2001 ◽

pp. 1701-1705 ◽

Author(s):

Asao Nakamura ◽

Hideo Nishino ◽

Yoshihisa Inoue

Keyword(s):

Asymmetric Synthesis ◽

Enantiomeric Excess ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

First Order ◽

Enantiomeric Enrichment ◽

First Order Kinetics ◽

The Relationship ◽

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Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis.

10.1002/chin.200448131 ◽

2004 ◽

Vol 35 (48) ◽

Author(s):

Itaru Sato ◽

Rie Sugie ◽

Yohei Matsueda ◽

Yuri Furumura ◽

Kenso Soai

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Asymmetric Autocatalysis

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Is Circularly Polarized Light an Effective Reagent for Asymmetric Synthesis?

10.1002/chin.200551241 ◽

2005 ◽

Vol 36 (51) ◽

Author(s):

Richard M. Pagni ◽

Robert N. Compton

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized

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A New Case of Asymmetric Synthesis Using Circularly Polarized Light

Israel Journal of Chemistry ◽

10.1002/ijch.197600015 ◽

1976 ◽

Vol 15 (1-2) ◽

pp. 78-81 ◽

Author(s):

J. F. Nicoud ◽

H. B. Kagan

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized

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Absolute asymmetric synthesis. II. (1) on the mechanism of the synthesis of nonracemic helicenes with circularly polarized light. Structural effects.

Tetrahedron Letters ◽

10.1016/s0040-4039(01)84804-8 ◽

1972 ◽

Vol 13 (22) ◽

pp. 2195-2198 ◽

Author(s):

William J. Bernstein ◽

Melvin Calvin ◽

Ole Buchardt

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Structural Effects ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Absolute Asymmetric Synthesis

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Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis

Angewandte Chemie International Edition ◽

10.1002/anie.200454162 ◽

2004 ◽

Vol 43 (34) ◽

pp. 4490-4492 ◽

Author(s):

Itaru Sato ◽

Rie Sugie ◽

Yohei Matsueda ◽

Yuri Furumura ◽

Kenso Soai

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Asymmetric Autocatalysis

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Synchronous enantiomeric enrichment of both reactant and product by absolute asymmetric synthesis using circularly polarized light. Part 3. Numerical simulation and experimental verification of the reversible asymmetric photoisomerization between methyl norbornadiene-2-carboxylate and methyl quadricyclane-1-carboxylate

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/b100753j ◽

2001 ◽

pp. 1706-1713 ◽

Author(s):

Hideo Nishino ◽

Asao Nakamura ◽

Hiroshi Shitomi ◽

Hideo Onuki ◽

Yoshihisa Inoue

Keyword(s):

Numerical Simulation ◽

Asymmetric Synthesis ◽

Experimental Verification ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Enantiomeric Enrichment ◽

Absolute Asymmetric Synthesis ◽

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Asymmetric Synthesis Utilizing Circularly Polarized Light Mediated by the Photoequilibrium of Chiral Olefins in Conjunction with Asymmetric Autocatalysis

Angewandte Chemie ◽

10.1002/ange.200454162 ◽

2004 ◽

Vol 116 (34) ◽

pp. 4590-4592 ◽

Author(s):

Itaru Sato ◽

Rie Sugie ◽

Yohei Matsueda ◽

Yuri Furumura ◽

Kenso Soai

Keyword(s):

Asymmetric Synthesis ◽

Polarized Light ◽

Circularly Polarized Light ◽

Circularly Polarized ◽

Asymmetric Autocatalysis

Download Full-text