Thiophenium-ylides: Synthesis and reactivity

2013 ◽  
Vol 67 (1) ◽  
Author(s):  
Aleš Machara ◽  
Jiří Svoboda
Keyword(s):  
Spectral Data ◽  
Tert Butyl ◽  
Rhodium Acetate

AbstractThe reaction of propanedioic acid, 2-diazo-1,3-bis(1,1-dimethylethyl) ester (di-tert-butyl diazomalonate) with a series of cyclopenta[b]thiophenes in the presence of catalytic rhodium acetate was studied. The resulting S—C ylides underwent a rearrangement to form a heterocycle with different topology; thialene, in very low yields. Experimental and spectral data for all compounds are provided.

Estimating Pigment Concentrations from Spectral Images Using an Encoder‐Decoder Neural Network

2020 ◽  
Vol 64 (3) ◽  
pp. 30502-1-30502-15
Author(s):  
Kensuke Fukumoto ◽  
Norimichi Tsumura ◽  
Roy Berns
Keyword(s):  
Neural Network ◽  
Neural Networks ◽  
Absorption Coefficient ◽  
Spectral Data ◽  
High Accuracy ◽  
Pigment Concentration ◽  
Scattering Coefficient ◽  
A Value ◽  
Input And Output ◽  
Pigment Concentrations

Abstract A method is proposed to estimate the concentration of pigments mixed in a painting, using the encoder‐decoder model of neural networks. The model is trained to output a value that is the same as its input, and its middle output extracts a certain feature as compressed information about the input. In this instance, the input and output are spectral data of a painting. The model is trained with pigment concentration as the middle output. A dataset containing the scattering coefficient and absorption coefficient of each of 19 pigments was used. The Kubelka‐Munk theory was applied to the coefficients to obtain many patterns of synthetic spectral data, which were used for training. The proposed method was tested using spectral images of 33 paintings, which showed that the method estimates, with high accuracy, the concentrations that have a similar spectrum of the target pigments.

Detection of potential aircraft icing regions with GOES multi-spectral data

1997 ◽  
Author(s):  
Gary Ellrod ◽  
James Nelson, III ◽  
Gary Ellrod ◽  
James Nelson, III
Keyword(s):  
Spectral Data ◽  
Aircraft Icing
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