We consider the problems of the complex application of the aluminium-yttrium binder in the fabrication of high-temperature resistant melting crucibles and investment molds thermoschemically resistant to titanium melts. The results of the contact interaction investigations of a molten titanium alloy with a material of aluminum-yttrium ceramics are presented. The usage of ceramic products of α-Al2O3–Y3Al5O12∙α-Al2O3 composition under conditions of high-temperature melting and pouring under vacuum minimizes the physicochemical interaction and significantly reduces the alpha case layer on cast products, thereby improving their operational properties.