scholarly journals Visible-Light-Mediated Photocatalytic Selective N-Methylation of Amines using CO2 under mild reaction condition via NH2-MIL-125 (Ti) MOF catalyst

2021 ◽  
Author(s):  
Jianguo liu ◽  
Xiuzhi Wei ◽  
Longlong Ma
Keyword(s):  
Visible Light ◽  
Metal Organic Framework ◽  
Synthesis Method ◽  
Selective Synthesis ◽  
Facile Synthesis ◽  
Reaction Conditions ◽  
Reaction Condition ◽  
Photocatalytic System ◽  
Metal Organic ◽  
Organic Framework

We herein describe a facile synthesis method of novel NH2-MIL-125 (Ti) metal organic framework as a photocatalyst, and the photochemical system was firstly developed for the direct N-methylation of amines under very mild reaction conditions of one bar CO2 and NaBH4. According to the optimization of reaction conditions, the selective synthesis of methylamines is achieved in good to excellent conversion and selectivity using visible light mediated photocatalytic system.

Metal–organic framework (MOF) composite materials for photocatalytic CO2 reduction under visible light

2021 ◽  
Author(s):  
Zhen Han ◽  
Yaomei Fu ◽  
Yingchao Zhang ◽  
Xiao Zhang ◽  
Xing Meng ◽  
...  
Keyword(s):  
Composite Materials ◽  
Visible Light ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Metal Organic ◽  
Organic Framework

We designed and synthesized TVPT-MOFs, combined with g-C3N4, and the yield of CO2 reduction could reach 56 μmol·g−1·h−1.

BiOCl-Coated UiO-66-NH2 Metal–Organic Framework Nanoparticles for Visible-Light Photocatalytic Cr(VI) Reduction

2021 ◽  
Vol 4 (4) ◽  
pp. 4037-4047
Author(s):  
Muhammad Bilal Hussain ◽  
Rashid Mehmood ◽  
Umair Azhar ◽  
Junnuan Wang ◽  
Lianghao Song
Keyword(s):  
Visible Light ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Visible Light Photocatalytic ◽  
Organic Framework

Metal-Organic Framework Photosensitized TiO2Co-catalyst: A Facile Strategy to Achieve a High Efficiency Photocatalytic System

2017 ◽  
Vol 23 (16) ◽  
pp. 3931-3937 ◽  
Author(s):  
Ming-Hua Xie ◽  
Rong Shao ◽  
Xin-Guo Xi ◽  
Gui-Hua Hou ◽  
Rong-Feng Guan ◽  
...  
Keyword(s):  
High Efficiency ◽  
Metal Organic Framework ◽  
Photocatalytic System ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Correction to: Facile synthesis of the magnetic metal–organic framework Fe3O4/Cu3(BTC)2 for efficient dye removal

2018 ◽  
Vol 17 (2) ◽  
pp. 1175-1175 ◽  
Author(s):  
Hui Sun ◽  
Hengyuan Zhang ◽  
Huimin Mao ◽  
Bin Yu ◽  
Jian Han ◽  
...  
Keyword(s):  
Dye Removal ◽  
Metal Organic Framework ◽  
Facile Synthesis ◽  
Magnetic Metal ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Photocatalytic Degradation of Methylene Blue and Methyl Orange by Y-PTC Metal-Organic Framework

2021 ◽  
Vol 7 (2) ◽  
pp. 129-141
Author(s):  
Adawiah Adawiah ◽  
Muhammad Derry Luthfi Yudhi ◽  
Agustino Zulys
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Metal Organic Framework ◽  
Light Irradiation ◽  
Bandgap Energy ◽  
Metal Organic ◽  
Organic Framework

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.

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