Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size
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Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.
2019 ◽
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2004 ◽
Vol 10
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pp. 1747-1751
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1998 ◽
Vol 1392
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pp. 101-108
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1992 ◽
Vol 96
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pp. 7458-7462
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2002 ◽
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pp. 80-87
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2011 ◽
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pp. 21383
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2003 ◽
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pp. 1522-1529
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1998 ◽
Vol 36
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pp. 755-760
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