Diels-Alder Additions to 2,2’-Biaceanthrylene
Keyword(s):
X Ray
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A series of Diels-Alder reactions between the diene 2,2’-biaceanthylene and several dienophiles is presented. The diene is a cyclopenta-fused polycyclic aromatic hydrocarbon with anthracene units linked by two cyclopentene rings. Depending on the dienophile, the major product was the result of a single addition (dimethyl acetylenedicarboxylate) or double addition (quinone, benzyne) to the diene. Single crystal X-ray analysis of the quinone-derivative shows a propeller-like structure composed of mixed enantiomers. The synthesis and photophysical properties of these compounds is presented.<br>
2021 ◽
2019 ◽
Vol 15
(S356)
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pp. 95-95
Keyword(s):
2019 ◽
2018 ◽
Vol 358
◽
pp. 236-245
2009 ◽
Vol 131
(44)
◽
pp. 16006-16007
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Keyword(s):
2019 ◽
Keyword(s):