Synthesis and Catalytic Activity of Rhodium(I) and Iridium(I) 4,5-Dibrominated N-Heterocyclic Carbenes
Keyword(s):
The synthesis and characterisation of another example of an air-stable carbene is described, in addition to the preparation of rhodium and iridium olefin and carbonyl complexes. The spectroscopic data indicates that these air-stable carbenes do not display reduced sigma-donor capacity of the carbenic centre. The catalytic applications of these carbenes are explored in the hydrosilylation and transfer hydrogenation processes.
2018 ◽
Keyword(s):
2013 ◽
Vol 740
◽
pp. 26-32
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Keyword(s):
2018 ◽
Vol 74
(11)
◽
pp. 1547-1552
Keyword(s):
2012 ◽
Vol 26
(12)
◽
pp. 663-670
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