scholarly journals Rhodium(III) Complexes Containing C4-Bound N-Heterocyclic Carbenes: Synthesis, Coordination Chemistry, and Catalytic Activity in Transfer Hydrogenation

2008 ◽  
Vol 27 (13) ◽  
pp. 3161-3171 ◽  
Author(s):  
Liangru Yang ◽  
Anneke Krüger ◽  
Antonia Neels ◽  
Martin Albrecht
Keyword(s):  
Catalytic Activity ◽  
Coordination Chemistry ◽  
Heterocyclic Carbenes ◽  
Transfer Hydrogenation

Synthesis and Catalytic Activity of Rhodium(I) and Iridium(I) 4,5-Dibrominated N-Heterocyclic Carbenes

2018 ◽  
Author(s):  
Samantha Furfari ◽  
Matthew Gyton ◽  
Marcus Cole
Keyword(s):  
Catalytic Activity ◽  
Spectroscopic Data ◽  
Heterocyclic Carbenes ◽  
Transfer Hydrogenation ◽  
Carbonyl Complexes ◽  
Donor Capacity ◽  
Catalytic Applications

The synthesis and characterisation of another example of an air-stable carbene is described, in addition to the preparation of rhodium and iridium olefin and carbonyl complexes. The spectroscopic data indicates that these air-stable carbenes do not display reduced sigma-donor capacity of the carbenic centre. The catalytic applications of these carbenes are explored in the hydrosilylation and transfer hydrogenation processes.

N-heterocyclic carbenes of iridium(I): ligand effects on the catalytic activity in transfer hydrogenation

2009 ◽  
pp. 7055 ◽  
Author(s):  
Sandra C. Zinner ◽  
Christoph F. Rentzsch ◽  
Eberhardt Herdtweck ◽  
Wolfgang A. Herrmann ◽  
Fritz. E. Kühn
Keyword(s):  
Catalytic Activity ◽  
Heterocyclic Carbenes ◽  
Transfer Hydrogenation ◽  
Ligand Effects

Synthesis and Catalytic Activity of Rhodium(I) and Iridium(I) 4,5-Dibrominated N-Heterocyclic Carbenes

2018 ◽  
Author(s):  
Samantha Furfari ◽  
Matthew Gyton ◽  
Marcus Cole
Keyword(s):  
Catalytic Activity ◽  
Spectroscopic Data ◽  
Heterocyclic Carbenes ◽  
Transfer Hydrogenation ◽  
Carbonyl Complexes ◽  
Donor Capacity ◽  
Catalytic Applications

The synthesis and characterisation of another example of an air-stable carbene is described, in addition to the preparation of rhodium and iridium olefin and carbonyl complexes. The spectroscopic data indicates that these air-stable carbenes do not display reduced sigma-donor capacity of the carbenic centre. The catalytic applications of these carbenes are explored in the hydrosilylation and transfer hydrogenation processes.

scholarly journals Dinucleating Schiff base ligand in Zn/4f coordination chemistry: synthetic challenges and catalytic activity evaluation

2018 ◽  
Vol 47 (13) ◽  
pp. 4486-4493 ◽  
Author(s):  
Stavroula I. Sampani ◽  
Sidonie Aubert ◽  
Martin Cattoen ◽  
Kieran Griffiths ◽  
Alaa Abdul-Sada ◽  
...  
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Coordination Chemistry ◽  
Schiff Base Ligand ◽  
Activity Evaluation

Synthetic challenges and catalytic activity evaluation of Zn/(Dy,Y) coordination clusters derived from a dinucleating Schiff base ligand.

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