scholarly journals Synthesis and Characterization of Silica Gel from Corn Cob Ash and Its Adsorption Study Toward Cu(II) Metal Ion

2020 ◽  
Vol 3 (2) ◽  
Author(s):  
Muhammad Fathurrahman
Keyword(s):  
Silica Gel ◽  
Metal Ion ◽  
Synthesis And Characterization ◽  
Corn Cob ◽  
Adsorption Study

Highly Selective Separation and Enrichment of Phosphopeptides by Uranyl-Salophen Immobilized Silica Gel Material

2015 ◽  
Vol 1095 ◽  
pp. 341-344 ◽  
Author(s):  
Can Hui Xu ◽  
Guang Liang Zhang ◽  
Xin Zhou ◽  
Xi Lin Xiao ◽  
Chang Ming Nie ◽  
...  
Keyword(s):  
Silica Gel ◽  
Metal Ion ◽  
High Selectivity ◽  
Separation Efficiency ◽  
Solid Phase ◽  
Tetradentate Ligand ◽  
Peptide Mixtures ◽  
New Material ◽  
Solid Phase Material

The characterization of phosphoproteins requires highly specific methods for the separation and enrichment of phosphopeptides. Here we report a novel metal ion-immobilized solid phase material for the separation and enrichment of phosphopeptides. The material is uranyl-salophen-silica gel (USSG) particles in which salophen is a tetradentate ligand of uranyl ion. In USSG salophen is connected on the surface of silica gel and uranyl is bound on the surface through its coordination with salophen. Phosphopeptides can be selectively retained by USSG because uranyl-salophen can bind phosphate moiety with strong affinity and high selectivity. The new material USSG has been successfully used for the separation of phosphopeptides from peptide mixtures with the separation efficiency of 97.0% to 97.4%.

scholarly journals Synthesis and characterization of Ni(II), Cu(II) and Co(III) complexes with polyamine-containing macrocycles bearing an aminoethyl pendant arm

2004 ◽  
Vol 69 (8-9) ◽  
pp. 641-649 ◽  
Author(s):  
Fouzia Rafat ◽  
M.Y. Siddiqi ◽  
K.S. Siddiqi
Keyword(s):  
Metal Ion ◽  
Magnetic Moments ◽  
Carbon Chain ◽  
Macrocyclic Complex ◽  
Synthesis And Characterization ◽  
Epr Spectrum ◽  
Pendant Arm ◽  
Octahedral Environment ◽  
Electrical Conductivities

Reaction of [M(ppn)2]X2 (where M = Cu(II), Ni(II), Co(II) and ppn = 1,3-diaminopropane) with formaldehyde and ethylenediamine in methanol results in the ready formation of a 16-membered macrocyclic complex. The complexes were characterized by elemental analysis, IR, EPR, electronic spectral data magnetic moments and conductance measurements. The Cu(II), Ni(II) and Co(III) complexes are coordinated axially with both pendant groups of the hexadentate macrocycle. These pendant donors are attached to the macrocycle by a carbon chain. The electrical conductivities of the Cu(II) and Ni(II) chelates indicated them to be 1:2 electrolytes whilst those of Co(III) is a 1:3 electrolyte in DMSO. The EPR spectrum of the copper complex exhibited G at 3.66, which indicates a considerable exchange interaction in the complex. Spectroscopic evidence suggests that in all of the complexes the metal ion is in an octahedral environment.

scholarly journals CAAC Boranes. Synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF3 and BH3

2010 ◽  
Vol 6 ◽  
pp. 709-712 ◽  
Author(s):  
Julien Monot ◽  
Louis Fensterbank ◽  
Max Malacria ◽  
Emmanuel Lacôte ◽  
Steven J Geib ◽  
...  
Keyword(s):  
Silica Gel ◽  
Synthesis And Characterization ◽  
Gel Chromatography ◽  
Nmr Analysis ◽  
X Ray ◽  
X Ray Crystallography ◽  
In Situ Formation ◽  
Silica Gel Chromatography

In situ formation of two cyclic (alkyl) (amino) carbenes (CAACs) followed by addition of BF3•Et2O provided the first two examples of CAAC–BF3 complexes: 1-(2,6-diisopropylphenyl)-3,5,5-trimethyl-3-phenylpyrrolidin-2-ylidene trifluoroborane, and 2-(2,6-diisopropylphenyl)-3,3-dimethyl-2-azaspiro[4.5]decan-1-ylidene trifluoroborane. These CAAC–BF3 complexes are robust compounds that are stable to ambient laboratory conditions and silica gel chromatography. They were characterized by spectroscopy and X-ray crystallography. In contrast, a CAAC complex with borane (BH3) was readily formed in situ according to 1H and 11B NMR analysis, but did not survive the workup conditions. These results set the stage for further studies of the chemistry of CAAC boranes.

Synthesis and Characterization of Lipophilic Organotins. Application to the Functionalization of Silica Gel

2007 ◽  
Vol 26 (23) ◽  
pp. 5576-5580 ◽  
Author(s):  
Marie-Laurence Dumartin ◽  
Hicham El Hamzaoui ◽  
Bernard Jousseaume ◽  
Marie-Claude Rascle ◽  
Thierry Toupance ◽  
...  
Keyword(s):  
Silica Gel ◽  
Synthesis And Characterization

Synthesis and characterization of highly luminescent N-doped carbon quantum dots for metal ion sensing

2018 ◽  
Vol 186 (1) ◽  
pp. 32-39 ◽  
Author(s):  
Sarita Devi ◽  
Amanjot Kaur ◽  
Sudipta Sarkar ◽  
Sujata Vohra ◽  
Sachin Tyagi
Keyword(s):  
Quantum Dots ◽  
Metal Ion ◽  
Carbon Quantum Dots ◽  
Synthesis And Characterization ◽  
Ion Sensing ◽  
Metal Ion Sensing

Synthesis and characterization of lignosulfonate/amino-functionalized SBA-15 nanocomposites for the adsorption of methylene blue from wastewater

2020 ◽  
Vol 44 (6) ◽  
pp. 2291-2302 ◽  
Author(s):  
Mohamed Abboud ◽  
Taher Sahlabji ◽  
Mohammad Abu Haija ◽  
Adel A. El-Zahhar ◽  
Samir Bondock ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Synthesis And Characterization ◽  
Adsorption Study ◽  
Mb Adsorption

The synthesis, characterization, and methylene blue (MB) adsorption study of a new lignosulfonate/amino-functionalized SBA-15 nanocomposite are described.

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