scholarly journals Oxidative Degradation of Methyl Green Dye by Cyanide Ion in Aqueous Perchloric Acid Medium; Kinetics, Thermodynamic and Mechanistic Approach

2019 ◽  
Vol VII (VIII) ◽  
Author(s):  
Sulaiman B.A. ◽  
Osunlaja A.A. ◽  
Mallam W.J. ◽  
Ndahi N.P. ◽  
Mindia A.A.
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Oxidative Degradation ◽  
Methyl Green ◽  
Cyanide Ion ◽  
Mechanistic Approach ◽  
Aqueous Perchloric Acid

Kinetics and Mechanism of the Autocatalyzed Oxidation of Theophylline by Permanganate in Aqueous Perchloric Acid Medium

2012 ◽  
Vol 41 (4) ◽  
pp. 567-580 ◽  
Author(s):  
Rajeshwari V. Hosahalli ◽  
Anita P. Savanur ◽  
Sharanappa T. Nandibewoor ◽  
Shivamurti A. Chimatadar
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Kinetics And Mechanism ◽  
Aqueous Perchloric Acid

scholarly journals Substrate Inhibition in Ruthenium(III) Catalyzed Oxidation of Propane-1,3-diol by Periodate in Acidic Medium: A Kinetic Study

2020 ◽  
Vol 32 (7) ◽  
pp. 1569-1575
Author(s):  
K.V.S. Koteswara Rao ◽  
R. Venkata Nadh ◽  
K. Venkata Ratnam
Keyword(s):  
Acid Medium ◽  
Perchloric Acid ◽  
Acidic Medium ◽  
Reaction Rate ◽  
Substrate Inhibition ◽  
Potassium Periodate ◽  
First Order ◽  
Plausible Mechanism ◽  
Aqueous Perchloric Acid ◽  
Catalyzed Oxidation

Ruthenium(III) catalyzed oxidation of propane-1,3-diol by potassium periodate was studied in aqueous perchloric acid medium. Orders of reaction with respect to concentrations of oxidant, substrate, acid and catalyst were determined. First order in oxidant and catalyst concentrations, and inverse fractional order in acid medium were observed. In addition, substrate inhibition (i.e. a decrease in reaction rate with an increase in substrate concentration) was observed. Effect of addition of salt and solvent was studied. Based on the studies of temperature variation, Arrhenius parameters were calculated. Plausible mechanism was also proposed based on observed kinetics.

Kinetic study of the nitrosation of 1,3-dialkylureas in aqueous-perchloric acid medium

2004 ◽  
Vol 36 (5) ◽  
pp. 273-279 ◽  
Author(s):  
Guillermo González-Alatorre ◽  
Salvador H. Guzmán-Maldonado ◽  
Eleazar M. Escamilla-Silva ◽  
Guadalupe Loarca-Piña ◽  
Carlos Hernández Benítez
Keyword(s):  
Kinetic Study ◽  
Acid Medium ◽  
Perchloric Acid ◽  
Aqueous Perchloric Acid
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