scholarly journals Electrode Material Effect on the Flash Ignition in Soda-Lime Silicate Glass

Ceramics ◽  
2021 ◽  
Vol 4 (1) ◽  
pp. 70-82
Author(s):  
Mattia Cipriani ◽  
Vincenzo M. Sglavo ◽  
Gian Domenico Sorarù ◽  
Mattia Biesuz

The need for sustainable solutions to reduce the carbon footprint of the ceramics and glass industry leads towards the development of new electric current-assisted technologies. Flash sintering-like processes in glasses allow a reduction of the softening temperature and could pave the way for new shaping technologies. Herein, we investigated the flash transition in soda-lime silicate glass using two different electrode materials, silver, and platinum. The high dielectric strength registered on samples tested with platinum electrodes undergoes a significant reduction when silver is used. In other words, in the case of silver electrodes, the flash ignition takes place at a lower onset field. Moreover, the Joule heating developed during the process can be turned from being highly inhomogeneous with Pt electrodes to homogeneous when Ag electrodes are used.

2011 ◽  
Vol 403-408 ◽  
pp. 70-74
Author(s):  
Kun Yang ◽  
Wei Hong Zheng ◽  
Jin Shu Cheng

Subscript textViscosity, coefficient of thermal expansion, glass transition temperature and dilatometric softening temperature of soda-lime-silicate glass doped with Li2O were investigated by the rotating crucible viscometer and dilatometry, the melting temperature and activation energy for viscous flow of the studied melt were derived on the basis of Arrhenius Equation, in order to reveal the effects of Li2O on the properties of soda-lime-silicate glass. The results showed that the viscosity of soda-lime-silicate glass was effectively decreased and the melting temperature decreased from 1457°C to 1420°C with the increase of Li2O from 0 to 1.0wt%, furthermore, the Tgand Tsreduced 30~40°C. The ΔT responded to the range of viscosity of glass formation (η=103-107Pa•s) increased from 309.84°C to 313.45°C, and the activation energy for viscous flow decreased form 178.47 kJ•mol-1to 168.34 kJ•mol-1. The CTE α(25~400°C)of specimen doped with 0.4% Li2O was 92.048×10-6°C-1and the lowest of the samples.


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