Vapour-Liquid Equilibria and Excess Thermodynamic Properties in Binary Systems of Cyclopentanone + Chloroalkanes in View of the Disquac and Unifac Group Contribution Models Extention

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Alexandru Birhala ◽  
Dana Dragoescu ◽  
Mariana Teodorescu
Keyword(s):  
Binary Systems ◽  
Excess Enthalpy ◽  
Group Contribution ◽  
Excess Properties ◽  
Structural Effects ◽  
Liquid Equilibrium ◽  
Excess Thermodynamic Properties ◽  
Different Types ◽  
Thermodynamic Excess Properties ◽  
Thermodynamic Excess

The data available in the literature and our recent data on vapour�liquid equilibrium (VLE), excess Gibbs energy, GE, and excess enthalpy, HE, for the homologous series of cyclopentanone + chloroalkane mixtures are examined in terms of the predictive group contribution models DISQUAC and UNIFAC. In our treatment, we present also how the structural effects and different types of molecular interactions are reflected by the thermodynamic excess properties of the mentioned series mixtures.

Thermodynamic Excess Properties of the 1-Alkylamine + Alkane and di-n-Alkylamine + Alkane Systems in Terms of an Associated Mixture Model with Equation of State Contribution

2003 ◽  
Vol 217 (6) ◽  
pp. 689-706 ◽  
Author(s):  
Andrzej J. Treszczanowicz ◽  
Teresa Treszczanowicz
Keyword(s):  
Equation Of State ◽  
Mixture Model ◽  
Binary Systems ◽  
Excess Enthalpy ◽  
Excess Properties ◽  
Flory Theory ◽  
State Contribution ◽  
Self Association ◽  
Thermodynamic Excess Properties ◽  
Thermodynamic Excess

AbstractThe model proposed by Treszczanowicz and Benson (1985) is applied for the description and interpretation of excess enthalpy HE, excess volume VE and excess molar isobaric heat capacity CEp of the binary systems formed by 1-alkylamines and dialkyl-amines with n-alkanes. In the model, the self-association contribution is described by an athermal associated mixture model with the continuous mode of association of the Mecke–Kempter type and the equation of state contribution described by the Flory theory. The three self-association parameters: enthalpy, entropy and volume are valid over the whole homologous series of 1-alkylamines and dialkylamines. The equation of state interaction parameters are correlated for both series of mixtures with the structure of the component molecules by using the Kehiaian–Guggenheim group contribution method. The model predicts reasonably well HE as well as VE for both these classes of mixtures.

Thermodynamic excess properties for binary mixtures of 1-chlorobutane with 2-butanol or 2-methyl-1-propanol

2001 ◽  
Vol 181 (1-2) ◽  
pp. 203-214 ◽  
Author(s):  
Rosa Garriga ◽  
Santiago Martı́nez ◽  
Pascual Pérez ◽  
Mariano Gracia
Keyword(s):  
Binary Mixtures ◽  
Excess Properties ◽  
Thermodynamic Excess Properties ◽  
Thermodynamic Excess

Speed of Sound, Density, and Related Thermodynamic Excess Properties of Binary Mixtures of Butan-2-one with C1–C4 n-Alkanols and Chloroform

2014 ◽  
Vol 59 (12) ◽  
pp. 4118-4132 ◽  
Author(s):  
Mikhail A. Varfolomeev ◽  
Ksenia V. Zaitseva ◽  
Ilnaz T. Rakipov ◽  
Boris N. Solomonov ◽  
Wojciech Marczak
Keyword(s):  
Binary Mixtures ◽  
Speed Of Sound ◽  
Excess Properties ◽  
Sound Density ◽  
Thermodynamic Excess Properties ◽  
Thermodynamic Excess
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