Stereo- and regioselectivity of the hetero-Diels–Alder reaction of nitroso derivatives with conjugated dienes
2016 ◽
Vol 12
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pp. 1949-1980
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Keyword(s):
The hetero-Diels–Alder reaction between a nitroso dienophile and a conjugated diene to give the 3,6-dihydro-2H-1,2-oxazine scaffold is useful for the synthesis of many biologically interesting molecules due to the diverse opportunities created by subsequent transformations of the resulting 1,2-oxazine ring. This review discusses the rationale for the observed regio- and stereoselectivity and the methods developed in recent years used to control and improve the stereo- and regioselectivity for the synthesis of 1,2-oxazine scaffolds.
Keyword(s):
1981 ◽
Vol 46
(15)
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pp. 3036-3040
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2005 ◽
Vol 690
(21-22)
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pp. 4794-4800
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Keyword(s):
Keyword(s):
2017 ◽
Vol 2017
(15)
◽
pp. 2205-2205
Keyword(s):
1999 ◽
Vol 72
(5)
◽
pp. 829-843
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Keyword(s):