Kinetics of Passive Film on Low Carbon Steel in Sodium Nitrate Solution by Numerical Analysis Method

2012 ◽  
Vol 457-458 ◽  
pp. 358-364 ◽  
Author(s):  
Ye Han ◽  
Zhen Duo Cui ◽  
Qiang Wei ◽  
Sheng Li Zhu ◽  
Xian Jin Yang

Passivation is a common means of material protection against corrosion applied in engineering. It is necessary to study the kinetics of the passive films forming to control the passivation process. A numerical analysis method is proposed and applied to study passivation kinetics of low carbon steel in sodium nitrate solution. Curve of passive film coverage against time is obtained and discussed. A maximum growth rate is found at initiating passive potential during the film forming process, and the film has already begun forming before the initiating passive potential arrived.

2020 ◽  
Author(s):  
I. O. Sinev ◽  
E. N. Beletsky ◽  
M. R. Tyutin ◽  
L. R. Botvina ◽  
O. V. Rybalchenko ◽  
...  

2020 ◽  
Vol 7 (1) ◽  
pp. 016554
Author(s):  
Siuli Dutta ◽  
Ashis K Panda ◽  
Amitava Mitra ◽  
Subrata Chatterjee ◽  
Rajat K Roy

2014 ◽  
Vol 21 (3) ◽  
pp. 335-341 ◽  
Author(s):  
Guang-ming Cao ◽  
Xiao-jiang Liu ◽  
Bin Sun ◽  
Zhen-yu Liu

2005 ◽  
Vol 475-479 ◽  
pp. 73-76
Author(s):  
Jun Jie Qi ◽  
Wang Yue Yang ◽  
Zu Qing Sun ◽  
X. Zhang

Quantitative characterization of microstructural development during deformation enhanced transformation in a low carbon steel was investigated on a Gleeble 1500 machine. General conclusions of the features of austenite transformation kinetics during deformation-enhanced transformation were formulated. It was shown that the process of deformation-enhanced transformation can be divided into three stages according to the characteristics of transformation kinetics: The kinetics equations of two early stages fitted well in J-M-A equation. The kinetics of the first stage obeys Cahn’s site saturation mechanism, with the value of kinetics parameter n of 4. Ferrite nucleates at austenite grain boundaries and triple points during the first stage. Kinetics of the second stage doesn’t obey Cahn’s theory, with the value of kinetics parameter n of 1-1.5, corresponding to ferrite nucleation repeatedly at areas with high stored energy in front of the ferrite/austenite interface. The kinetics doesn’t obey the law of J-M-A equation any more in the final stage, and only few nucleation sites left at this moment.


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