Patterned crystal growth and heat wave generation in hydrogels

The crystallization of metastable liquid phase change materials releases stored energy as latent heat upon nucleation and may therefore provide a triggerable means of activating downstream processes that respond to changes in temperature. In this work, we describe a strategy for controlling the fast, exothermic crystallization of sodium acetate from a metastable aqueous solution into trihydrate crystals within a polyacrylamide hydrogel whose polymerization state has been patterned using photomasks. A comprehensive experimental study of crystal shapes, crystal growth front velocities and evolving thermal profiles showed that rapid growth of long needle-like crystals through unpolymerized solutions produced peak temperatures of up to 45˚C, while slower-crystallizing polymerized solutions produced polycrystalline composites and peaked at 30˚C due to lower rates of heat release relative to dissipation in these regions. This temperature difference in the propagating heat waves, which we describe using a proposed analytical model, enables the use of this strategy to selectively activate thermoresponsive processes in predefined areas.

Effect of Annealing on Microstructure and Corrosion Behavior of Interstitial Free Steel

Interstitial free steels with various grain sizes and textures were prepared by cold-rolling followed by an annealing process. The effect of grain size, crystallographic orientations and stored energy on corrosion behavior of interstitial free steel was investigated. It was found that the deformed microstructure and dislocation boundaries were consumed by recrystallizing grains during annealing. The average grain size increase ranging from 0.61 μm to 11 μm and the volume fraction of recrystallized grains was about 96% after annealing for 64 h; meanwhile, the γ fiber was the dominated recrystallized texture component. The stored energy gradually decreased due to the reduction in dislocation density by annealing. The potentiodynamic polarization and Nyquist plots show that the corrosion potential exhibits a more positive shift and depressed capacitive semicircle radius increase with rising annealing time. The 64 h annealed specimens had the biggest depressed semicircle in the Nyquist plots and the highest positive corrosion potential, which indicates the enhancement of corrosion resistance. Such an improvement of corrosion resistance is attributed to the increase in the volume fraction of the γ fiber and decrease in the stored energy.

Analysis of energy losses in electric transmis-sion taking into account the Sommerfeld – Kononenko effect

The use of an electric drive in modern vehicles allows solving a number of problems related to the issues of environmental and energy security of the country. However, this approach imposes a number of practical limitations. Among them there is such a significant factor as the limitation on the stored energy in the traction batteries and, as a consequence, the limitation of the mileage on one charge. One of the ways to solve this problem is to reduce mechanical losses associated with the appearance of resonance phenomena in rotating transmission elements and having an unbalanced mass. Goal. The goal is to assess the influence of the Sommerfeld – Kononenko effect on energy indicators during the transfer of rotation from the electric motor to the drive wheel of an electric vehicle. To achieve this goal, it is necessary to determine the law of motion of the rotor of an electric motor and a car wheel using the energy approach and a model of complex motion. Methodology. To solve the problem of determining the law of rotation of an electric motor rotor, a dynamic model of an eccentric vibrator is adopted. The study takes into account the fluctuations in the angular velocity of the shaft with Hooke's hinge when the shaft axis deviates from horizontal positions. It is proposed to apply an energy approach using a model of complex motion to determine the law of rotation of an electric motor rotor and a wheel. Results. The dependence of the speed of rotation of the wheel of an electric vehicle is determined in accordance with the dynamic model under the conditions of fluctuations in the angular speed of transmission elements with Hooke's hinge when the wheel axis deviates from the horizontal position. Practical value. An energy approach is proposed for finding losses in a complex motion model to determine the law of rotation of an electric motor rotor and a wheel. An analytical dependence of additional energy losses caused by wheel unbalance on vehicle mileage and wheel unbalance is found.

Optimization of Nano-Additive Characteristics to Improve the Efficiency of a Shell and Tube Thermal Energy Storage System Using a Hybrid Procedure: DOE, ANN, MCDM, MOO, and CFD Modeling

Using nano-enhanced phase change material (NePCM) rather than pure PCM significantly affects the melting/solidification duration and the stored energy, which are two critical design parameters for latent heat thermal energy storage (LHTES) systems. The present article employs a hybrid procedure based on the design of experiments (DOE), computational fluid dynamics (CFD), artificial neural networks (ANNs), multi-objective optimization (MOO), and multi-criteria decision making (MCDM) to optimize the properties of nano-additives dispersed in a shell and tube LHTES system containing paraffin wax as a phase change material (PCM). Four important properties of nano-additives were considered as optimization variables: volume fraction and thermophysical properties, precisely, specific heat, density, and thermal conductivity. The primary objective was to simultaneously reduce the melting duration and increase the total stored energy. To this end, a five-step hybrid optimization process is presented in this paper. In the first step, the DOE technique is used to design the required simulations for the optimal search of the design space. The second step simulates the melting process through a CFD approach. The third step, which utilizes ANNs, presents polynomial models for objective functions in terms of optimization variables. MOO is used in the fourth step to generate a set of optimal Pareto points. Finally, in the fifth step, selected optimal points with various features are provided using various MCDM methods. The results indicate that nearly 97% of the Pareto points in the considered shell and tube LHTES system had a nano-additive thermal conductivity greater than 180 Wm−1K−1. Furthermore, the density of nano-additives was observed to be greater than 9950 kgm−3 for approximately 86% of the optimal solutions. Additionally, approximately 95% of optimal points had a nano-additive specific heat of greater than 795 Jkg−1K−1.

Nonlinear dynamics of proton beams with hollow electron lens in the CERN high-luminosity LHC

The design stored beam energy in the CERN high-luminosity large hadron collider (HL-LHC) upgrade is about 700 MJ, with about 36 MJ in the beam tails, according to estimates based on scaling considerations from measurements at the LHC. Such a large amount of stored energy in the beam tails poses serious challenges on its control and safe disposal. In particular, orbit jitters can cause significant losses on primary collimators, which can lead to accidental beam dumps, magnet quenches, or even permanent damage to collimators and other accelerator elements. Thus, active control of the diffusion speed of halo particles is necessary and the use of hollow electron lenses (HELs) represents the most promising approach to handle overpopulated tails at the HL-LHC. HEL is a very powerful and advanced tool that can be used for controlled depletion of beam tails, thus enhancing the performance of beam halo collimation. For these reasons, HELs have been recently included in the HL-LHC baseline. In this paper, we present detailed beam dynamics calculations performed with the goal of defining HEL specifications and operational scenarios for HL-LHC. The prospects for effective halo control in HL-LHC are presented.

Review: Deformed and recrystallized structures in FCC materials

The evolution in the field of recrystallization related studies in FCC metals is summarized in this paper. The process of recrystallization which is initiated by stored energy is provided by dislocations. However, dislocations are introduced during the process of deformation, hence both aspects are covered, as well as the kinetics of recrystallization is well elaborated. The key features of recrystallization: role of misorientations; deformation and recrystallization textures; are described and most importantly recent issues on recrystallization of FCC metals are documented in this paper. The final remarks contain the future aspects of studies in the field of recrystallization of materials with FCC crystal structure.

Thermal Analysis of the Solar Collector Cum Storage System Using a Hybrid-Nanofluids

The main problem in the solar energy field is the storage of thermal energy. To divert this problem, it was suggested to use a flat-plat solar collector which also serves as a storage system; this solution will reduce the size of a refrigerating machine that we are studying. A high stored energy density is only possible if we through use latent heat of phase change. Thermal analysis has been developed for this type of storage collector for near-steady state conditions using a nanofluid heat storage substance depended on KNO3–NaNO3 binary salt mixture as PCM and a mix of Al2O3–SiO2 as nanoparticle, from which the new Hottel-Whillier-Bliss equations have been used for efficient flat plate collector. Computations were achieved for a large variety of parameters to verify the significance of the created model.

Thermal Characterization of Medium-Temperature Phase Change Materials (PCMs) for Thermal Energy Storage Using the T-History Method

To reduce energy consumption and increase energy efficiency in the building sector, thermal energy storage with phase change materials (PCMs) is used. The knowledge of the thermophysical properties and the characteristics of PCMs (like their enthalpy changes and the distribution of stored energy over a specified temperature range) is essential for proper selection of the PCM and optimal design of the latent thermal energy store (LHTES). This paper presents experimental tests of the thermophysical properties of three medium-temperature PCMs: OM65, OM55, RT55, which can be used in domestic hot water installations and heating systems. Self-made test chambers with temperature control using Peltier cells were used to perform measurements according to the T-history method. In this way the temperature range of the phase transition, latent heat, specific heat capacity, enthalpy and the distributions of stored energy of the three PCMs were determined. The paper also presents measurements of the thermal conductivity of these PCMs in liquid and solid state using a self-made pipe Poensgen apparatus. The presented experimental tests results are in good agreement with the manufacturers’ data and the results of other researchers obtained with the use of specialized instruments. The presented research results are intended to help designers in the selection of the right PCM for the future LHTES co-working with renewable energy systems, waste heat recovery systems and building heating systems.