Oxidative Esterification of Methacrolein to Methyl Methacrylate over La Doped Catalyst

2012 ◽  
Vol 512-515 ◽  
pp. 2390-2393
Author(s):  
Gui Hua Li ◽  
An Feng Wang
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Methyl Methacrylate ◽  
Catalytic Performance ◽  
Catalyst Amount ◽  
Oxidative Esterification ◽  
Additional Amount ◽  
La Doped

In this present work, rare earth elements La was added to catalysts for the oxidative esterification of methacrolein (MAL) to methyl methacrylate(MMA). Catalysts were characterized by means of BET techniques. Effects of La proportion, material liquid pH and catalyst amount on catalytic performance were investigated. The results indicated that the addation of La in appropriate proportion could improve the catalyst’s activity. 1.0% was found to be the optimum La additional amount. Under the condition of reation temperature 323K, w%(catalyst) 3.6%, proportion of La in the catalyst 1%, pH of material liquid 10.0 the MMA yield could reached up to 89.8%.

Bis(phosphinimino)methanide borohydride complexes of the rare-earth elements as initiators for the polymerization of methyl methacrylate: combined experimental and computational investigations

2011 ◽  
Vol 2 (8) ◽  
pp. 1728 ◽  
Author(s):  
Sophie M. Guillaume ◽  
Pierre Brignou ◽  
Nicolas Susperregui ◽  
Laurent Maron ◽  
Magdalena Kuzdrowska ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Methyl Methacrylate ◽  
The Rare Earth

Flame spectra of the rare-earth elements*

1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
The Rare Earth

ESTIMATION OF THE ABUNDANCE AND DISTRIBUTION OF RARE EARTH ELEMENTS IN SOIL AROUND KADUNA REFINING AND PETROCHEMICAL COMPANY USING NUCLEAR TECHNIQUE

2020 ◽  
Vol 4 (2) ◽  
pp. 599-604
Author(s):  
Michael A. Onoja ◽  
P. H. Bukar ◽  
C. U. Omeje ◽  
A. M. Adamu
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Nuclear Technique ◽  
Flood Plains ◽  
Economic Exploitation ◽  
Rare Elements ◽  
Petrochemical Company ◽  
The Moment ◽  
Abundance And Distribution ◽  
Natural Pattern

Instrumental neutron activation analysis (INAA) technique was used to investigate the abundance and distribution of rare earth elements (REE) in soil around Kaduna Refinery. The aim of the study is to assess the rare elements potential of Nigeria for economic exploitation. Five REEs (La, Dy, Eu, Yb, and Lu) were detected in varying concentrations ranging from a minimum of 0.6 µg/g (Lu) to a maximum of 249.0 µg/g (La). The elements existed with trends consistent with the natural pattern of REEs in soil, showing significant Eu and Dy anomalies which characterize upper plains and flood plains. The levels of REEs in soil in the study area were generally slightly above background levels, with minimal (La, Dy, and Eu), moderate (Yb), and significant (Lu) enrichments and trending: Lu ˃Yb ˃ Eu ˃ Dy ˃ La. The abundance of the REEs investigated cannot establish a potential of Nigeria for economic exploitation of the mineral, hence, rare earth project in the study area is not viable at the moment.

Sc, Y, La-Lu Rare Earth Elements

1986 ◽  
Author(s):  
Ingeborg Hinz ◽  
Peter Kuhn ◽  
Ursula Vetter ◽  
Eberhard Warkentin
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements
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